Synthesis and Thermal Behavior of New Precursors for B-C-N Ceramics

Abstract

Abstract:

Three new borazine derivatives, 2,4,6-tri(allylamino)borazine (CH2=CHCH2NHBNH)3 (1), 2,4,6-tri(3-ethynylanilino)borazine (CH´CC₆H₄NHBNH)₃(2), and 2,4,6-tri(4-propargyl oxyanilino)borazine (CH´CCH₂OC₆H₄NHBNH)₃ (3) were synthesized by reaction of 2,4,6-trichloro-borazine Cl₃B₃N₃H₃ (TCB) with corresponding primary amines, respectively. Their thermal behavior was studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). These molecules were easily crosslinked via thermal
polymerization of reactive ethynyl or vinyl groups. The pyrolytic residues of borazines were investigated by X-ray photoelectron spectroscopy (XPS), powder X-ray diffraction (XRD), and scanning electron microscopy (SEM). The analytic results indicated that B-C-N ceramics were formed upon pyrolysis of the borazines under an inert atmosphere.

Key words: Precursors, Thermal properties, B-C-N ceramic

Shaohua Dong Weijian Han Yongming Luo Tong Zhao Caihong Xu. Synthesis and Thermal Behavior of New Precursors for B-C-N Ceramics[J]. J Mater Sci Technol, 2010, 26(3): 228-233.

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