Abstract: The variation of the dielectric constant e' and the dielectric loss e" of polyesteramide, alkyd polyesteramide and alkyd varnish dry films were measured within the frequency range from 105 to 107 Hz and the temperature range from 20 to 50℃. The varnish films were subjected to accelerated ageing by heating at 110℃ for diferent durations. The efect of the accelerated ageing on e' and e" were measured. The activation energy and the entropy change of dielectric relaxation for the dry films before and after ageing were also calculated. All the results obtained were recorded and discussed in correlation with the molecular structure of the investigated varnishes.