Abstract: An anomalous Kerr loop was observed in an oriented LaBaMno film annealed in oxygen. Many tiny crystal columns were observed with scanning tunneling microscope and magnetic force microscope. The magnetic moment m in the column is perpendicular outward to the surface, which forms a surface phase with spin pinning state. This spin pinning results in the obvious asymmetrical Kerr loop of magneto-optical effect when the magnetic field is in the two opposite directions vertical to the surface.