J Mater Sci Technol ›› 2009, Vol. 25 ›› Issue (06): 789-794.

• Articles • Previous Articles     Next Articles

Correlation of Magnetic Properties of Co/Cr Bilayer Thin Films with Grain Boundary Diffusion

Gaowu Qin, Bo Yang, Wenli Pei, Yuping Ren   

  1. Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), Northeastern University, Shenyang 110004, China
  • Received:2008-04-22 Revised:2009-07-17 Online:2009-11-28 Published:2009-11-24
  • Contact: Gaowu Qin
  • Supported by:

    the National Natural Science Foundation of China (No. 50671020)
    the Chinese Ministry of Education (Nos. 108039 and IRT0713)

Abstract:

The microstructure and magnetic properties of Co/Cr bilayer films were examined before and after post-deposition annealing by using transmission electron microscopy (TEM), X-ray diffraction (XRD) technique and vibrating sample magnetometer (VSM). A model of grain boundary (GB) Cr-rich phase growth involving GB diffusion derived from the Cr underlayer was proposed to elucidate the kinetics of the paramagnetic Cr-rich phase growth along Co GBs within the Co layer. The correlation of the GB Cr-rich phase formation with the magnetic Co grain isolation and accordingly, improvement of magnetic properties was experimentally investigated and discussed in detail. Our analysis results are well consistent with previous micromagnetic simulations on the improvement of magnetic properties by the magnetic grain isolation. The results provide some insights into the processing-structure-property relationships of the Co/Cr bilayer films, and thus suggest that the magnetic grain isolation be feasible not only in longitudinal recording media, but also be effective in tuning the exchange coupling of magnetic grains in perpendicular recording media via the GB diffusion from underlayer and/or overlayer.

Key words: Magnetic recording media, Grain boundary diffusion, Magnetic isolation, Co/Cr thin films