J Mater Sci Technol ›› 2009, Vol. 25 ›› Issue (04): 489-491.

• Articles • Previous Articles     Next Articles

Effects of Substrate Temperature on the Growth of Polycrystalline Si Films Deposited with SiH4+Ar

Hua Cheng1,3), Aimin Wu2)†, Jinquan Xiao1),  Nanlin Shi1), Lishi Wen1)†   

  1. 1) Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
    2) Dalian University of Technology, Dalian 116024, China
    3) Armor Technique Institute of PLA, Changchun 130117, China
  • Received:2008-05-06 Revised:2008-12-05 Online:2009-07-28 Published:2009-10-10
  • Contact: Aimin Wu; Lishi Wen

Abstract:

Polycrystalline silicon (poly-Si) films were deposited using Ar diluted SiH4 gaseous mixture by electron cyclotron resonance plasma-enhanced chemical vapor deposition (ECR-PECVD). The effects of the substrate temperature on deposition rate, crystallinity, grain size and the configuration of H existing in poly-Si film were investigated. The results show that, comparing with H2 dilution, Ar dilution could significantly decrease the concentration of H on the growing surface. When the substrate temperature increased, the deposition rate increased and the concentration of H decreased monotonously, but the crystallinity and the grain size of poly-Si films exhibited sophisticated trends. It is proposed that the crystallinity of the films is determined by a competing balance of the self-diffusion activity of Si atoms and the deposition rate. At substrate temperature of 200°C, the deposited film exhibits the maximum poly-Si volume fraction of 79%. Based on these results, higher substrate temperature is suggested to prepare the poly-Si films with advanced stability and compromised crystallinity at high deposition rate.

Key words: Poly-Si films, ECR-PECVD, Substrate temperature, Ar-dilution