J. Mater. Sci. Technol. ›› 2026, Vol. 264: 306-320.DOI: 10.1016/j.jmst.2025.11.028

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Influence of Cu content on precipitation behavior and mechanical properties of Al-Mg-Si alloys during prolonged aging process

Xian Wu, Zhi-Ping Guan*, Feng Qiu*   

  1. Key Laboratory of Automobile Materials, Ministry of Education & School of Materials Science and Engineering, Jilin University, Changchun 130025, China
  • Received:2025-08-26 Revised:2025-10-27 Accepted:2025-11-18 Published:2026-09-10 Online:2026-09-02
  • Contact: *E-mail addresses: guanzp@jlu.edu.cn (Z.-P. Guan), qiufeng@jlu.edu.cn (F. Qiu) .

Abstract: Cu additions to Al-Mg-Si alloys enable a desirable combination of high strength and thermal stability. This study investigates the microstructure and mechanical response of Al-1.0Mg-1.2Si (wt.%) with 0, 0.8, and 1.6 wt.% Cu during artificial aging at 175 °C for up to 400 h using Vickers hardness testing, tensile testing, and transmission electron microscope techniques, with quantitative statistics of precipitate morphology, number density, and volume fraction. The Cu-containing alloys reach peak yield strengths of ∼366 MPa (0.8Cu) and ∼373 MPa (1.6Cu), maintaining ∼350 MPa with ∼13 % elongation after 200 h aging, demonstrating an excellent strength-ductility balance. The enhanced tensile properties arise from stronger initial solid-solution strengthening and fine, dense precipitates. Prolonged aging of the 1.6Cu alloy produces plate-like θ′-Al2Cu phase, whereas the 0.8Cu alloy shows no θ′ under the same conditions, thereby indicating a composition-time window for θ′ precipitation at 175 °C. Precipitation-kinetics analyses based on classical nucleation theory support the thermodynamic/kinetic feasibility of the θ′ phase in the higher-Cu system. Overall, these results clarify how Cu content governs competing precipitation pathways and the resulting mechanical properties of Al-Mg-Si-Cu alloys.

Key words: Al-Mg-Si-Cu alloy, Mechanical properties, Precipitation strengthening, Aging precipitation kinetics