J. Mater. Sci. Technol. ›› 2026, Vol. 266: 62-75.DOI: 10.1016/j.jmst.2025.10.078

• Research article • Previous Articles     Next Articles

Rapid densification behavior and sintering enhancing mechanism of 2D C/SiBCN-Ti with exceptional mechanical property/manufacture cost ratio

Zhang Yijuna, Xu Jingjunb, Bi Jingqingb, Yan Hana,*, Liu Yuc,*, Zhang Yiduana, Han Weijiand, Zhang Zhongweia,*   

  1. aInstitute of Advanced Structure Technology, Beijing Institute of Technology, Beijing 100081, China;
    bShenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China;
    cState Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China;
    dLaboratory of Advanced Polymer Materials, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Received:2025-07-24 Revised:2025-09-27 Accepted:2025-10-19 Published:2026-09-20 Online:2025-11-29
  • Contact: *E-mail addresses: yanh@bit.edu.cn (H. Yan), yu_liu@csu.edu.cn (Y. Liu),zhangzhongw@163.com (Z. Zhang).

Abstract: Ensuring considerable mechanical properties while reducing costs presents a critical challenge in the manufacture of ceramic matrix composites. This research proposes a rapid fabrication method named ViSfP-TiCOP (High Viscosity Solvent-free Precursor Combined Elemental Titanium Controlled Pyrolysis). This high cost-effectiveness benefits from excellent mechanical properties and low fabrication costs. C/SiBCN-7 vol % Ti fabricated by ViSfP-TiCOP attained the flexural strength (1200 °C) of 397 MPa and interlaminar shear strength of 23.25 MPa in a short preparation period (5 PIP cycles). Not only that, contributed to its limited raw material expenses (2D carbon fiber fabric and high precursor utilization) and minimal equipment requirements (pressureless pyrolysis, < 1400 °C), the processing cost of ViSfP-TiCOP is remarkably small. ViSfP-TiCOP exhibits an exceptional mechanical property/manufacture cost ratio compared to the conventional PIP process. The high mechanical property of C/SiBCN-Ti is attributed to the formation of a TiCN transition gradient interface between SiBCN and Ti, which enhances sintering activity, while the extremely short densification cycle benefits from in-situ gaseous carbon-fixation and nitrogen-fixation reactions of elemental Ti, resulting in higher volume yield for SiBCN-Ti. Owing to these mechanisms, ViSfP-TiCOP provides a particularly cost-effective method for the large-scale manufacture of CMCs.

Key words: CMCs, Mechanical property/manufacture cost ratio, Microstructure, Flexural strength