J. Mater. Sci. Technol. ›› 2026, Vol. 253: 159-165.DOI: 10.1016/j.jmst.2025.08.004

• Research article • Previous Articles     Next Articles

Two-dimensional wide-bandgap NbMoO6 for field-effect transistors and UV photodetectors

Yong Zhanga,1, Lin Wangb,1, Pin Zhaob,1, Xiujun Wangb, Yatong Wangb, Minxing Dub, Xiaosheng Fangc,*   

  1. aSchool of Electronic and Information Engineering, Suzhou University of Technology, Changshu 215500, China;
    bDivision of Advanced Materials, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, China;
    cCollege of Smart Materials and Future Energy and State Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai 200438, China
  • Received:2025-06-11 Revised:2025-07-28 Accepted:2025-08-10 Published:2026-05-10 Online:2026-05-07
  • Contact: *E-mail address: xshfang@fudan.edu.cn (X. Fang).
  • About author:1 These authors contributed equally to this work.

Abstract: Two-dimensional (2D) wide-bandgap oxides show great potential as candidates for next-generation multifunctional devices. High dielectric (high-κ) and photoactive 2D NbMoO6 (NMO) is engineered for field-effect transistors and ultraviolet (UV) photodetectors. The NMO nanosheets are synthesized by solid-phase calcination, proton exchange, and liquid-phase exfoliation process. NMO, with a high dielectric constant (∼31.1), can serve as a gate dielectric for a semiconducting single-walled carbon nanotubes (s-SWCNTs) field-effect transistor, displaying a high on/off ratio of 5 × 104 at a low operating voltage of -5 V. Meanwhile, an individual NMO nanosheet photodetector exhibits high responsivity (210 A/W) and high detectivity (2.58×1012 Jones) at 3 V at 320 nm. Furthermore, NMO nanosheet film photodetectors show great potential for application in UV image sensing. This work not only provides a new candidate for 2D electronic and optoelectronic devices but also introduces a feasible strategy to explore 2D oxides for various applications.

Key words: UV photodetectors, Wide-bandgap oxides, NbMoO6 nanosheets