Abstract: The effective thermal management of lithium-ion batteries is the key to ensuring their fast charging-discharging, safe and efficient operation. Herein, inspired by transpiration-driven water transport in plants, we report a highly hygroscopic needle-punched carbon fiber felt (HS/CFF) with high evaporative cooling efficiency and fire resistance for the safe operation of lithium-ion batteries working at ultrahigh-rate conditions. The three-dimensional fiber skeleton structure constructed by needle punching in the carbon fiber felt enables effective water transport and storage in HS/CFF, without any water leakage. At an ultra-high discharge rate of 10 C, HS/CFF can reduce the maximum temperature of commercial lithium-ion batteries by 18 °C, and can keep the battery temperature below 60 °C. During 500 cycles of charge-discharge, HS/CFF maintains stable evaporative heat dissipation performance, which helps to improve the safety of lithium-ion batteries and extend their service life. Moreover, HS/CFF remains non-combustible even under exposure to a flame (600-700 °C) for 10 min, and the HS/CFF can be reused after the burning test, with the original excellent heat dissipation effect unchanged. This flexible, fire-resistant cooling material offers a promising avenue for low-energy intelligent thermal management of lithium-ion batteries and other heat-generating electronic devices.

Key words: Passive evaporative cooling, Battery thermal management, Carbon fiber felt, Fire resistance, Hygroscopic