J. Mater. Sci. Technol. ›› 2025, Vol. 218: 95-107.DOI: 10.1016/j.jmst.2024.08.006

• Research Article • Previous Articles     Next Articles

Formation mechanism of defects in Invar 36/MnCu functionally graded material fabricated by directed energy deposition

Yijie Penga,b, Wei Fana,b,c, Dapeng Haoa,b, Zhe Fenga,b, Mingji Danga,b, Zhiwei Haoa,b, Hua Tana,b,*, Fengying Zhangd, Xin Lina,b   

  1. aState Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072, China;
    bKey Laboratory of Metal High Performance Additive Manufacturing and Innovative Design, MIIT China, Northwestern Polytechnical University, Xi'an 710072, China;
    cSingapore Centre for 3D Printing, School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798, Singapore;
    dSchool of Material Science and Engineering, Chang'an University, Xi'an 710064, China
  • Received:2024-05-05 Revised:2024-08-15 Accepted:2024-08-20 Published:2025-05-20 Online:2024-09-03
  • Contact: *E-mail address: tanhua@nwpu.edu.cn (H. Tan).

Abstract: The fabrication of Invar/MnCu functionally graded material (FGM) through directed energy deposition (DED) can satisfy the demands for precision devices in aerospace, providing lightweight properties and integrating thermal stability and vibration damping capabilities. However, basic research on Invar/MnCu FGM is still lacking, hindering its potential applications. To address this gap, this study was conducted using mixed powders and consistent process parameters to print experiments for Invar/MnCu FGM and homogeneous samples. Phases, microstructures, compositions, and thermal expansion properties were thoroughly examined. Three types of defects were detected in the Invar/MnCu FGM sample: unmelted Invar 36 powders, cracks, and pores. The mechanism of unmelted powders was deeply discussed, attributing it to material properties influencing laser absorptivity, the required time for melting powder, and effects on solidus temperature. The mechanism of cracks was also discussed, attributing it to the γ-Fe dendritic structure causing low melting point metal to form an intergranular liquid film, harmful secondary phases mismatched with the terminal alloy, and obvious tensile stresses during the DED process. Additionally, an effective strategy was proposed to reduce defects in Invar/MnCu FGM. After optimization, the specimens exhibited excellent tensile properties, with a yield strength of 262 ± 5 MPa, an ultimate tensile strength of 316 ± 7 MPa, and an elongation of 3 % ± 1 %. This research provides valuable references and insights for subsequent work, offering robust support for better understanding and designing other FGM.

Key words: Additive manufacturing, Directed energy deposition, Functionally graded materials, Invar alloy, MnCu alloy