J. Mater. Sci. Technol. ›› 2024, Vol. 182: 176-186.DOI: 10.1016/j.jmst.2023.10.016

• Research Article • Previous Articles     Next Articles

Relationship between solidification path, microstructure evolution and solidification cracking behavior of Mg-Al-Ca alloy during TIG welding

Sensen Chaia,b, Qingwei Daia,*, Shiyu Zhongc, Qingshan Yanga, Limeng Yina, Dingfei Zhangb, Jingkai Fengd, Qian Lib,e,f,g,*   

  1. aSchool of Metallurgy and Materials Engineering, Chongqing University of Science and Technology, Chongqing 401331, China;
    bCollege of Materials Science and Engineering, Chongqing University, Chongqing 400045, China;
    cDepartment of Mechanical Engineering, City University of Hong Kong, Hong Kong 999077, SAR, China;
    dXI'AN Rare Metal Materials Institute Co., Ltd., Xi'an 710016, China;
    eState Key Laboratory of Advanced Special Steels & Shanghai Key Laboratory of Advanced Ferrometallurgy & School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China;
    fNational Engineering Research Center for Magnesium Alloy, Chongqing University, Chongqing 400044, China;
    gNational Key Laboratory of Advanced Casting Technologies, Chongqing University, Chongqing 400044, China
  • Received:2023-07-21 Revised:2023-10-03 Accepted:2023-10-06 Published:2024-05-20 Online:2024-05-15
  • Contact: *E-mail addresses: daiqingwei@cqust.edu.cn (Q. Dai), cquliqian@cqu.edu.cn (Q. Li)

Abstract: The high-strength and creep-resistant Mg-Al-Ca-Mn alloys have broad application prospects. However, solidification cracking occurs in these alloys in certain conditions and the origin is still unclear. This work investigated the relationship between the solidification path, microstructure evolution and solidification cracking behavior of the Mg-xAl-2Ca-Mn alloys during tungsten inert gas (TIG) welding. Results show that when the fusion zone's Ca/Al mass ratio ranges from 0.4 to 1.64, solidification cracking occurs at a Ca/Al mass ratio of ∼0.7. As the Ca/Al mass ratio approaches this value, the grain size increases, and the Laves phases are reduced gradually. The early formed Laves phases play an important role in promoting dendrite segmentation, refining grain size and enhancing grain boundaries. When a solidification path delays the formation of Laves phases, the Laves phases will be reduced accompanied by grain coarsening. In such a solidifying microstructure, intergranular cavitation is easy to occur, and the resistance of the semi-solid alloy to crack propagation is severely reduced.

Key words: Magnesium alloy, Welding, Solidification cracking, Solidification path, Laves phase