J. Mater. Sci. Technol. ›› 2023, Vol. 151: 204-218.DOI: 10.1016/j.jmst.2023.02.001

• Research Article • Previous Articles     Next Articles

Enhanced strength and toughness of high nitrogen stainless bearing steel by controlling interstitial partitioning via V-microalloying

Lingfeng Xiaa, Huabing Lia,b,*, Hao Fenga,c, Zhouhua Jianga,b, Hongchun Zhua,c, Shucai Zhanga, Xiaodong Wangd   

  1. aSchool of Metallurgy, Northeastern University, Shenyang 110819, China;
    bKey Laboratory for Ecological Metallurgy of Multimetallic Ores (Ministry of Education), Northeastern University, Shenyang 110819, China;
    cLiaoning Province Engineering Research Center for Technologies of Low-Carbon Steelmaking, Northeastern University, Shenyang 110819, China;
    dState Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
  • Received:2022-12-22 Revised:2023-02-11 Accepted:2023-02-12 Published:2023-07-10 Online:2023-02-16
  • Contact: * E-mail address: lihb@smm.neu.edu.cn (H. Li).

Abstract: High-nitrogen stainless bearing steel (HNSBS) with ultra-high tensile strength (∼ 2403 MPa) and good toughness (∼80.0 J) was obtained by V-microalloying, overcoming the strength-toughness trade-off of conventional V-free HNSBS. In this work, since V-microalloying facilitated the enrichment of interstitial atoms (C and N) in precipitates, the content of interstitial atoms in the matrix was reduced accordingly (i.e., interstitial partitioning). On the one hand, V-microalloying reduced the substantial intergranular precipitates and transformed the precipitates from M23C6 + M2N into V-containing M23C6 + M2N + MN with multi-scale particle sizes, causing a coupling strengthening effect, which contributed to the toughness and additional strength increase. On the other hand, V-microalloying controlled interstitial partitioning, effectively refined coarse retained austenite (RA), increased the fraction of dislocation martensite, and reduced the fraction of twin martensite. The more film-like RA and dislocation martensite with high dislocation density coordinated plastic deformation and prevented crack propagation, thus obviously enhancing the strength and toughness of 0.2 V steel. This study provides a new route to develop high-performance HNSBS for aerospace applications.

Key words: High-nitrogen stainless bearing steel, Vanadium microalloying, Interstitial partitioning, Strength and toughness