Copper ions-mediated dynamic redox-responsive microgels synergize with silicone for efficient and sustainable antibacterial properties

doi:10.1016/j.jmst.2022.10.032

Abstract

Abstract: The antifouling of marine facilities placed below the waterline is a key constraint to the development of the marine economy. Currently, commercial Cu₂O-based antifouling coatings still have defects such as agglomeration, oxidation, short duration and high dosage. For this reason, we developed for the first time a triple antifouling system consisting of Cu₂O@poly(NIPAM-co-DAm) (Cu₂O@PND) dynamic redox microgels triggered by copper ions and polydimethylsiloxane (PDMS). The catechol groups of PND nanogels can chelate Cu²⁺ and reduce it in situ to obtain Cu₂O@PND microgels, which guarantees the stable release of Cu⁺. Furthermore, Cu₂O remains stable and free from oxidation because of the electron transfer between PND and Cu²⁺. Finally, superior antifouling performance was achieved by combining the stable Cu⁺ released from Cu₂O, in situ conversion of PND to hydrogel, and its oxidation to produce active substances and H₂O₂, and PDMS coating with low surface energy.

Key words: Hydrogel, Copper ions, Dynamic redox, Silicone, Efficient-sustainable release, Antibacterial

Huali Li, Liuqin Zhang, Xiaohu Zhang, Shuwen Luo, Baoshan Yang, Min Wu, Wei-Hua Li, Fa-Qian Liu. Copper ions-mediated dynamic redox-responsive microgels synergize with silicone for efficient and sustainable antibacterial properties[J]. J. Mater. Sci. Technol., 2023, 143: 253-267.

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