Zwitterionic glycine modified Fe/Mg-layered double hydroxides for highly selective and efficient removal of oxyanions from polluted water

doi:10.1016/j.jmst.2019.12.034

Abstract

Abstract:

Zwitterionic glycine was employed to modify Fe/Mg-layered double hydroxides (LDH) to realize an G-Fe/Mg-LDH adsorbent with high adsorption capacities of oxygen-containing anions including As(V), P(V) and Cr(VI). When the Fe/Mg mole ratio was 0.02 mol/0.02 mol, the G-Fe/Mg-LDH has a good adsorption performance. The optimum adsorption pH value of G-Fe/Mg-LDH for oxygen-containing anions was 6. The selectivity of three oxygen-containing anions was Cr(VI)<P(V)<As(V), and the maximum adsorption capacity of As(V) reached as high as 830 mg g ^-1, outperforming most previously reported efficient adsorbents for As(V). The adsorption process followed Freundlich isotherm and pseudo-second-order kinetic model, suggesting the heterogeneous adsorption and chemical adsorption of the G-Fe/Mg-LDH. When the initial concentration of As(V) was 200 mg L ^-1, the adsorption efficiency of G-Fe/Mg-LDH was 82.5% within 30 min. This study provides a way to modify the LDHs for environmental remediation.

Key words: lycine, Water treatment, Arsenic, Oxyanions, Selective adsorption

Xiaofeng Shi, Chao Wang, Jiaoxia Zhang, Li Guo, Jing Lin, Duo Pan, Juying Zhou, Jincheng Fan, Tao Ding, Zhanhu Guo. Zwitterionic glycine modified Fe/Mg-layered double hydroxides for highly selective and efficient removal of oxyanions from polluted water[J]. J. Mater. Sci. Technol., 2020, 51: 8-15.

Figures/Tables 12

Fig. 1. Representative SEM images of G-Fe/Mg-LDH-1, G-Fe/Mg-LDH-2, G-Fe/Mg-LDH-3 and Fe/Mg-LDH.

Fig. 2. Isotherms of adsorption and desorption of N2 and the pore size distribution curve of the obtained G-Fe/Mg-LDH-1 (a), G-Fe/Mg-LDH-2 (b), G-Fe/Mg-LDH-3 (c) and Fe/Mg-LDH (d).

Fig. 3. FT-IR spectra (a) and XRD patterns (b) of G-Fe/Mg-LDH-1, G-Fe/Mg-LDH-2, G-Fe/Mg-LDH-3 and Fe/Mg-LDH.

Fig. 4. XPS survey spectrum of G-Fe/Mg-LDH (a) and the corresponding high-resolution XPS spectrum of Fe (b), Mg (c) and N (d).

Table 1 Adsorption of samples toward the three mixed ions.

Sorbent	Mixed ions	C₀ (mg L^-1)	C_e (mg L^-1)-1 h	Removal efficiency (%)	K_d (mL g^-1)
G-Fe/Mg-LDH-1	As(V)	30	10.3	65.7	4.8 × 10³
	Cr(VI)	30	23.5	21.7	6.9 × 10²
	P(V)	30	22.4	25.3	8.4 × 10²
G-Fe/Mg-LDH-2	As(V)	30	9.5	68.3	5.4 × 10³
	Cr(VI)	30	23.7	21.0	6.6 × 10²
	P(V)	30	22.6	24.7	8.2 × 10²
G-Fe/Mg-LDH-3	As(V)	30	0.01	100	7.5 × 10⁶
	Cr(VI)	30	17.2	42.7	1.9 × 10³
	P(V)	30	16.5	45.0	2.0 × 10³
Fe/Mg-LDH	As(V)	30	20.8	30.7	1.1 × 10³
	Cr(VI)	30	28.8	4.0	1.0 × 10²
	P(V)	30	27.9	7.0	1.9 × 10²
V = 25 mL, m = 10 mg

Fig. 5. Effect of initial solution pH on the adsorption capacity of G-Fe/Mg-LDH-3.

Table 2 Adsorption of G-Fe/Mg-LDH-3 toward the As(V) with different concentrations.

C₀ (mg L^-1)	10	50	100	200	300	500	700	800	1000
C_e (mg L^-1)	0	0	5	8	15	175	370	468	668
q_e (mg g^-1)	25	125	237.5	480	712.5	812.5	825	830	830
R² of Langmuir isotherm model: 0.989; R² of Freundlich isotherm model: 0.9410.

Fig. 6. Langmuir (a) and Freundlich (b) isotherm models of G-Fe/Mg-LDH-3 on As(V).

Fig. 7. Pseudo-first order (a) and pseudo-second order (b) kinetic plot for the adsorption of G-Fe/Mg-LDH-3 on As(V).

Fig. 8. Effects of contact time on the adsorption capacities of G-Fe/Mg-LDH-3.

Table 3 Adsorption of G-Fe/Mg-LDH-3 toward the As(V) with different stirring time.

Time (min)	5	10	20	30	60	120	180
C_e (mg L^-1)	100	50	35	20	10	8	8
q_t (mg g^-1)	250	375	412.5	450	475	480	480

Table 4 Maximum adsorptive capacity of different adsorbents for As(V).

No.	Samples	Maximum adsorptive capacity (mg g^-1)	References
1	G-Fe/Mg-LDH-1	608.2	-
2	G-Fe/Mg-LDH-2	715.6	-
3	G-Fe/Mg-LDH-3	830	-
4	Chitosan-coated Na-X zeolite	63.23	[87]
5	EDA-GMA-g-NCF	217.39	[88]
6	ZrO(OH)(2)/CNTs	124.6	[89]
7	Biologically mackinawite	237.45	[90]

References 90

[1]	Y.H. Zhao, X.L. Tian, B. Zhao, Y. Sun, H. Guo, M. Dong, H. Liu, X. Wang, Z. Guo, A. Umar, H. Hou , Sci. Adv. Mater., 10(2018), pp. 1793-1804.
[2]	Y.G. Tong, S.X. Bai, Y.L. Hu, X.B. Liang, Y.C. Ye, Q.H. Qin , Ceram. Int., 44(2018), pp. 3692-3698.
[3]	Y.G. Tong, P.B. Qi, X.B. Liang, Y.X. Chen, Y.L. Hu, Z.F. Hu , Materials, 11(2018), p. 1250.
[4]	Y.G. Tong, Z.H. Cai, S.X. Bai, Y.L. Hu, M.Y. Hua, W. Xie, Y.C. Ye, Y. Li , Ceram. Int., 44(2018), pp. 16577-16582.
[5]	Y.G. Tong, W.T. Zhu, S.X. Bai, Y.L. Hu, X.Q. Xie, Y. Li , Mater. Sci. Eng. A, 735(2018), pp. 166-172.
[6]	B.M. Li, Y. Yan, C.T. Shen, Y. Yu, Q.H. Wang, M.K. Liu , Nanoscale, 10(2018), pp. 16217-16230.
[7]	M. Liu, Q. Meng, Z. Yang, X. Zhao, T. Liu , Chem. Commun., 54(2018), pp. 5090-5093.
[8]	H. Gu, X. Xu, M. Dong, P. Xie, Q. Shao, R. Fan, C. Liu, S. Wu, R. Wei, Z. Guo , Carbon, 147(2019), pp. 550-558.
[9]	A.J. Berndt, J. Hwang, M.D. Islam, A. Sihn, A.M. Urbas, Z. Ku, S.J. Lee, D.A. Czaplewski, M. Dong, Q. Shao, S. Wu, Z. Guo, J.E. Ryu , Polymer, 176(2019), pp. 118-126.
[10]	Y. Ma, Z. Zhuang, M. Ma, Y. Yang, W. Li, J. lin, M. Dong, S. Wu, T. Ding, Z. Guo , Polymer, 182 ( 2019),Article 121808.
[11]	Y. Wang, D. Jiang, L. Zhang, B. Li, C. Sun, H. Yan, Z. Wu, H. Liu, J. Zhang, J. Fan, H. Hou, T. Ding, Z. Guo , Nanotechnology, 31 ( 2019), Article 025704.
[12]	Y. Guo, X. Yang, K. Ruan, J. Kong, M. Dong, J. Zhang, J. Gu, Z. Guo , ACS Appl. Mater. Interf., 11(2019), pp. 25465-25473.
[13]	X. Huang, R. Yin, L. Qian, W. Zhao, H. Liu, C. Liu, J. Fan, H. Hou, J. Zhang, Z. Guo , Ceram. Int., 45(2019), pp. 17784-17792.
[14]	B. Lin, Z. Lin, S. Chen, M. Yu, W. Li, Q. Gao, M. Dong, Q. Shao, S. Wu, T. Ding, Z. Guo , Dalton Trans., 48(2019), pp. 8279-8287.
[15]	Z. Lin, B. Lin, Z. Wang, S. Chen, C. Wang, M. Dong, Q. Gao, Q. Shao, T. Ding, H. Liu, S. Wu, Z. Guo , ChemCatalChem., 11(2019), pp. 2217-2222.
[16]	J. Yang, W. Yang, X. Wang, M. Dong, H. Liu, E.K. Wujcik, Q. Shao, S. Wu, T. Ding, Z. Guo, ., Macromol. Chem. Phys 220 ( 2019), Article 1800567.
[17]	J. Ren, Q. Luo, Q. Hou, H. Chen, T. Liu, H. He, J. Wang, Q. Shao, M. Dong, S. Wu, N. Wang, J. Lin, Z. Guo , ChemElectrChem., 6(2019), pp. 3167-3174.
[18]	H. Gu, X. Xu, J. Cai, S. Wei, H. Wei, H. Liu, D.P. Young, Q. Shao, S. Wu, T. Ding, Z. Guo , Chem. Commun., 55(2019), pp. 10068-10071.
[19]	Y. Zhai, J. Wang, Q. Gao, Y. Fan, C. Hou, Y. Hou, H. Liu, Q. Shao, S. Wu, L. Zhao, T. Ding, F. Dang, Z. Guo, J. Catal., 377(2019), pp. 534-542.
[20]	K. Le, Z. Wang, F. Wang, Q. Wang, Q. Shao, V. Murugadoss, S. Wu, W. Liu, J. Liu, Q. Gao, Z. Guo , Dalton Trans., 48(2019), pp. 5193-5202.
[21]	Z.J. Shi, G.F. Xu, J. Deng, M.Y. Dong, V. Murugadoss, C.T. Liu, Q. Shao, S.D. Wu, Z.H. Guo , Green Chem. Lett. Rev., 12(2019), pp. 235-243.
[22]	L. Ma, Y. Zhu, P. Feng, G. Song, Y. Huang, H. Liu, J. Zhang, J. Fan, H. Hou, Z. Guo, , Compos. Part B 176 ( 2019), Article 107078.
[23]	S.D. Wu, J.M. Liu, B.B. Cui, Y.L. Li, Y.K. Liu, B. Hu, L.H. He, M.H. Wang, Z.H. Zhang, K. Tian, Y.P. Song , Electrochim. Acta, 299(2019), pp. 231-244.
[24]	M.K. Liu, Y.Q. Liu, Y. Yan, F.S. Wang, J.H. Liu, T.X. Liu , Chem. Commun., 53(2017), pp. 9097-9100.
[25]	Y. Ma, C. Hou, H. Zhang, Q. Zhang, H. Liu, S. Wu, Z. Guo , Electrochim. Acta, 315(2019), pp. 114-123.
[26]	C. Hou, J. Wang, W. Du, J. Wang, Y. Du, C. Liu, J.X. Zhang, H. Hou, F. Dang, L. Zhao, Z. Guo, J. Mater. Chem. A, 7(2019), pp. 13460-13472.
[27]	G. Zhu, X. Cui, Y. Zhang, S. Chen, M. Dong, H. Liu, Q. Shao, T. Ding, S. Wu, Z. Guo , Polymer, 172(2019), pp. 415-422.
[28]	K. Le, M. Gao, W. Liu, J. Liu, Z. Wang, F. Wang, V. Murugadoss, S. Wu, T. Ding, Z. Guo, Electrochim. Acta, 323 ( 2019),Article 134826.
[29]	M.M. Wang, Y.J. Zheng, T. Jing, J.Z. Tian, P.S. Chen, M.Y. Dong, C. Wang, C. Yan, C.T. Liu, T. Ding, W. Xie, Z.H. Guo , Sci. Adv. Mater., 11(2019), pp. 756-763.
[30]	Z.J. Shi, C.H. Wu, Y.W. Gu, Y. Liang, G.F. Xu, H. Liu, J.X. Zhang, H. Hou, J.Y. Zhang, Z.H. Guo , Sci. Adv. Mater., 11(2019), pp. 1198-1205.
[31]	M. Liu, B. Li, H. Zhou, C. Chen, Y. Liu, T. Liu , Chem. Commun., 53(2017), pp. 2810-2813.
[32]	K. Gong, X. Li, H. Liu, X. Cheng, D. Sun, Q. Shao, M. Dong, C. Liu, S. Wu, T. Ding, B. Qiu, Z. Guo , Carbon, 156(2020), pp. 320-328.
[33]	Y.Q. Guo, K.P. Ruan, X.T. Yang, T.B. Ma, J. Kong, N.N. Wu, J.X. Zhang, J.W. Gu, Z.H. Guo, J. Mater. Chem. C, 7(2019), pp. 7035-7044.
[34]	D.W. Jiang, Y. Wang, B. Li, C.Y. Sun, Z.J. Wu, H. Yan, L.X. Xing, S.L. Qi, Y.C. Li, H. Liu, W. Xie, X.J. Wang, T. Ding, Z.H. Guo, Macromol. Mater. Eng., 304 ( 2019), Article 1900074.
[35]	L. Qi, Z.L. Ma, J.H. Liang, Z.L. Xiao, M.Y. Dong, J.X. Zhang, Z.H. Guo, J.C. Fan, T. Ding, C.T. Liu, J. Mater. Res. Technol., 8(2019), pp. 4264-4272.
[36]	Y. Liu, M. Narayanasamy, C. Yang, M. Shi, W. Xie, H. Wu, C. Yan, H. Hou, Z. Guo, J. Mater. Res., 34(2019), pp. 3030-3039.
[37]	K.K. Miao, X.L. Luo, W. Wang, J.L. Guo, S.F. Guo, F.J. Cao, Y.Q. Hu, P.M. Chang, G.D. Feng, Micropor. Mesopor. Mater., 289 ( 2019), Article 109640.
[38]	D. Pan, S.S. Ge, J.K. Zhao, J.Y. Tian, Q. Shao, L. Guo, X.M. Mai, T.T. Wu, V. Murugadoss, H. Liu, T. Ding, S. Angaiah, Z.H. Guo , Ind. Eng. Chem. Res., 58(2019), pp. 836-848.
[39]	J. Tian, Q. Shao, J. Zhao, D. Pan, M. Dong, C. Jia, T. Ding, T. Wu, Z. Guo, J. Colloid Interf. Sci., 541(2019), pp. 18-29.
[40]	P. Yang, L.J. Yang, Q. Gao, Q. Luo, X.C. Zhao, X.M. Mai, Q.L. Fu, M.Y. Dong, J.C. Wang, Y.W. Hao, R.Z. Yang, X.C. Lai, S.D. Wu, Q. Shao, T. Ding, J. Lin, Z.H. Guo , Chem. Commun., 55(2019), pp. 9011-9014.
[41]	B. Song, Q. Wang, L. Wang, J. Lin, X. Wei, V. Murugadoss, S. Wu, Z. Guo, T. Ding, S. Wei, J. Colloid Interf. Sci., 559 ( 2020), pp. 124-133.
[42]	H. Sun, Z. Yang, Y. Pu, W. Dou, C. Wang, W. Wang, X. Hao, S. Chen, Q. Shao, M. Dong, S. Wu, T. Ding, Z. Guo, J. Colloid Interf. Sci., 547(2019), pp. 40-49.
[43]	D. Mohan, C.U. Pittman, J. Hazard. Mater., 137(2006), pp. 762-811.
[44]	M.A. Barakat , Arab. J. Chem., 4(2011), pp. 361-377.
[45]	K. Li, Z. Huang, S. Zhu, S. Luo, L. Yan, Y. Dai, Y. Guo, Y. Yang , Appl. Catal. B, 243(2019), pp. 386-396.
[46]	X. Yang, L. Yan, Y. Wu, Y. Liu, L. Shao, J. Membrane Sci., 589 ( 2019), Article 117223.
[47]	Y. Huang, X. Zeng, L. Guo, J. Lan, L. Zhang, D. Cao , Sep. Purif. Technol., 194(2018), pp. 462-469.
[48]	S. Xu, Y. Lv, X. Zeng, D. Cao , Chem. Eng. J., 323(2017), pp. 502-511.
[49]	S. Zhao, Y. Yuan, Q. Yu, B. Niu, J. Liao, Z. Guo, N. Wang , Angew. Chem. Int. Edit., 28(2019), pp. 14979-14985.
[50]	C. Huang, X. Shi, C. Wang, L. Guo, M. Dong, G. Hu, J. Lin, T. Ding, Z. Guo , Int. J. Biol. Macromol., 140(2019), pp. 1167-1174.
[51]	X. Shi, C. Wang, Y. Ma, H. Liu, S. Wu, Q. Shao, Z. He, L. Guo, T. Ding, Z. Guo , Powder Technol., 356(2019), pp. 726-734.
[52]	Y.H. Yuan, Q.H. Yu, S. Yang, J. Wen, Z.H. Guo, X.L. Wang, N. Wang, Adv. Sci., 6 ( 2019), Article 1900961.
[53]	R. Nagarajah, K.T. Wong, G. Lee, K.H. Chu, Y. Yoon, N.C. Kim, M. Jang , Sep. Purif. Technol., 174(2017), pp. 290-300.
[54]	E.P. Mistova, H. Jelinek , Sep. Sci. Technol., 52(2017), pp. 787-791.
[55]	X.L. Luo, F. Pei, W. Wang, H.M. Qian, K.K. Miao, Z. Pan, Y.S. Chen, G.D. Feng , Micropor. Mesopor. Mater., 262(2018), pp. 148-153.
[56]	X.L. Luo, Z. Pan, F. Pei, Z.P. Jin, K.K. Miao, P.F. Yang, H.M. Qian, Q. Chen, G.D. Feng, J. Ind. Eng. Chem., 59(2018), pp. 410-415.
[57]	C. Lou, T. Jing, J. Tian, Y. Zheng, J. Zhang, M. Dong, C. Wang, C. Hou, J. Fan, Z. Guo, J. Mater. Res., 34(2019), pp. 2964-2975.
[58]	G. Xu, C. Jia, Z. Shi, R. Liang, C. Wu, H. Liu, C. Yan, J. Fan, H. Hou, T. Ding, Z. Guo , Sci. Adv. Mater., 12(2020), pp. 304-311.
[59]	Y. Zhang, Q. Shao, B. Zhao, B. Zhang, V. Murugadoss, S. Wu, T. Ding, Z. Guo, Colloid Surf. A, 583 ( 2019), Article 123965.
[60]	Y. Li, H.Y. Bi, X.Q. Shi , Environ. Eng. Sci., 32(2015), pp. 666-675.
[61]	Z. Xia, L. Baird, N. Zimmerman, M. Yeager , Appl. Surf. Sci., 416(2017), pp. 565-573.
[62]	Y. Yuan, Q. Yu, J. Wen, C. Li, Z. Guo, X. Wang, N. Wang , Angew. Chem. Int. Edit., 58(2019), pp. 11785-11790.
[63]	Y.X. Qian, Y.H. Yuan, H.L. Wang, H. Liu, J.X. Zhang, S. Shi, Z.H. Guo, N. Wang, J. Mater. Chem. A, 6(2018), pp. 24676-24685.
[64]	L. Ma, N. Li, G. Wu, G. Song, X. Li, P. Han, G. Wang, Y. Huang , Appl. Surf. Sci., 433(2018), pp. 560-567.
[65]	S.W. Li, P.P. Yang, X.H. Liu, J.X. Zhang, W. Xie, C. Wang, C.T. Liu, Z.H. Guo, J. Mater. Chem. A, 7(2019), pp. 16902-16911.
[66]	H. Qi, M. Teng, M. Liu, S. Liu, J. Li, H. Yu, C. Teng, Z. Huang, H. Liu, Q. Shao, A. Umar, T. Ding, Q. Gao, Z. Guo, J. Colloid Interf. Sci., 539(2019), pp. 332-341.
[67]	M. Zhang, J. Meng, Q. Liu, S. Gu, L. Zhao, M. Dong, J. Zhang, H. Hou, Z. Guo, J. Mater. Res., 34(2019), pp. 3050-3060.
[68]	N.D. Rudd, H. Wang, E.M. Fuentes-Fernandez, S.J. Teat, F. Chen, G. Hall, Y.J. Chabal, J. Li, ACS Appl. Mater. Interf., 8(2016), pp. 30294-30303.
[69]	S. Radi, Y. Toubi, M. Bacquet, S. Degoutin, Y.N. Mabkhot, Y. Garcia , RSC Adv., 6(2016), pp. 34212-34218.
[70]	X. Shi, C. Wang, Y. Ma, H. Liu, S. Wu, Q. Shao, Z. He, L. Guo, T. Ding, Z. Guo , Powder Technol., 356(2019), pp. 726-734.
[71]	D. Pan, S. Ge, J. Tian, Q. Shao, L. Guo, H. Liu, S. Wu, T. Ding, Z. Guo, Chem. Rec. (2019), .
[72]	L. L. Alfonso Tobón, S. Fuente. M. M. Branda, Appl. Surf. Sci., 465(2019), pp. 715-723.
[73]	D. Yan, H.J. Li, H.Q. Cai, M. Wang, C.C. Wang, H.B. Yi, X.B. Min , Chemosphere, 194(2018), pp. 117-124.
[74]	L. Tan, H. Li, M. Liu , RSC Adv., 8(2018), pp. 12870-12878.
[75]	B. Zhang, L. Luan, R. Gao, F. Li, Y. Li, T. Wu , Colloid. Surf. A, 520(2017), pp. 399-408.
[76]	G. Hu, T. Emrick, J. Am. Chem. Soc., 138(2016), pp. 1828-1831.
[77]	Y. Tian, H.G. Liu, Q. Yuan, Y.H.Li.Q. Tang, W.Z. Zhang, Q. Bart Van der, X.L. Wang, ACS Nano, 9(2015), pp. 7488-7496.
[78]	S.A. Ali, S.A. Haladu , React. Funct. Polym., 73(2013), pp. 796-804.
[79]	L. Ma, Q. Wang, S.M. Islam, Y. Liu, S. Ma, M.G. Kanatzidis, J. Am. Chem. Soc., 138(2016), pp. 2858-2866.
[80]	R.R. Shan, L.G. Yan, K. Yang, Y.F. Hao, B. Du, J. Hazard. Mater., 299(2015), pp. 42-49.
[81]	Y. Shen, X. Zhao, X. Zhang, S. Li, D. Liu, L. Fan , Desalin. Water Treat., 57(2014), pp. 2064-2072.
[82]	D.H.D. Naumann, H. Labischinski, Nature, 351(1991), pp. 81-82.
[83]	M. Guerreroperez, M. Herrera, I. Malpartida, M. Larrubia, L. Alemany , Catal. Today, 118(2006), pp. 360-365.
[84]	M. Kac̆urákováa, P.Capeka. V. Sasinkováa, N. Wellnerb, A. Ebringerováa, Carbohyd. Polym., 43(2000), pp. 195-203.
[85]	H. Asiabi, Y. Yamini, M. Shamsayei, J. Hazard. Mater., 339(2017), pp. 239-247.
[86]	D. Chen, Y. Li, J. Zhang, W. Li, J. Zhou, L. Shao, G. Qian, J. Hazard. Mater., 243(2012), pp. 152-160.
[87]	C. Han, T. Yang, H. Liu, L. Yang, Y. Luo , Environ. Sci. Pollut. R, 26(2019), pp. 10106-10116.
[88]	S. Korpayev, C. Kavakli, S. Tilki, P. Akkas Kavakli , Environ. Sci. Pollut. R, 25(2018), pp. 34610-34622.
[89]	D. Liu, S. Deng, A. Maimaiti, B. Wang, J. Huang, Y. Wang, G. Yu, J. Colloid Interf. Sci., 511(2018), pp. 277-284.
[90]	J. Zhou, S. Chen, J. Liu, R.L. Frost , Chem. Eng. J., 354(2018), pp. 237-244.