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Hydrochlorination of Acetylene Using SiC Foam Supported Structured C/Au Catalysts

Xiaodan Yang, Chunhai Jiang, Zhenming Yang, Jinsong Zhang   

  1. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
  • Received:2013-10-25 Revised:2013-11-17 Online:2014-05-15 Published:2014-05-15
  • Contact: J. Zhang
  • Supported by:

    This work was financially supported by the National Key Technology R&D Program of China with Grant No. 2011BAE03B07.

Abstract:

AuCl3 loaded structured catalysts were prepared on SiC foam supported with pre-coated activated carbon layers. The catalytic properties of the structured catalysts towards hydrochlorination of acetylene were tested in a fixed-bed reactor with the AuCl3 loaded on activated carbon pellets as a reference. For isopyknic catalysts, the structured catalyst with only one fifth of the Au amount as that was used on the reference catalyst exhibited even a little higher acetylene conversion and much better stability than the latter no matter what the gas hourly space velocities of acetylene were used. The results indicated that the more homogeneous distribution of AuCl3 particles and better heat transfer along the fixed-bed reactor originated from the low pressure drop and high thermal conductivity of the SiC foam supported structured catalysts might be able to account for their improved efficiency and stability. It is believed that these novel structured C/Au catalysts can be potentially applied in VCM industrialization in view of their greatly reduced cost and much prolonged life.