J. Mater. Sci. Technol. ›› 2018, Vol. 34 ›› Issue (11): 2197-2204.DOI: 10.1016/j.jmst.2018.04.008

Special Issue: Graphene 2018

• Orginal Article • Previous Articles     Next Articles

Enhanced efficiency of graphene-silicon Schottky junction solar cell through inverted pyramid arrays texturation

Jiajia Qiua, Yudong Shangc, Xiuhua Chenc, Shaoyuan Liab*(), Wenhui Maab, Xiaohan Wanb, Jia Yangab, Yun Leiab, Zhengjie Chenb   

  1. a State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China
    b Institute of New Energy/Silicon Metallurgy and Silicon Material Engineering Research Center of Universities in Yunnan Province, Kunming University of Science and Technology, Kunming 650093, China
    c Faculty of Physical Science and Technology, Yunnan University, Kunming 650091, China
  • Received:2017-08-07 Revised:2017-09-19 Accepted:2017-09-27 Online:2018-11-20 Published:2018-11-26
  • Contact: Li Shaoyuan

Abstract:

Nanostructures of silicon are gradually becoming hot candidate due to outstanding capability for trapping light and improving conversion efficiency of solar cell. In this paper, silicon nanowires (SiNWs) and silicon inverted pyramid arrays (SiIPs) were introduced on surface of Gr-Si solar cell through silver and copper-catalyzed chemical etching, respectively. The effects of SiNWs and SiIPs on carrier lifetime, optical properties and efficiency of Gr-SiNWs and Gr-SiIPs solar cells were systematically analyzed. The results show that the inverted pyramid arrays have more excellent ability for balancing antireflectance loss and surface area enlargement. The power conversion efficiency (PCE) and carrier lifetime of Gr-SiIPs devices respectively increase by 62% and 34% by comparing with that of Gr-SiNWs solar cells. Finally, the Gr-SiIPs cell with PCE of 5.63% was successfully achieved through nitric acid doping. This work proposes a new strategy to introduce the inverted pyramid arrays for improving the performance of Gr-Si solar cells.

Key words: Graphene-Si solar cell, Silver/copper-assisted chemical etching, Silicon nanowires, Silicon inverted pyramid arrays