J Mater Sci Technol ›› 2005, Vol. 21 ›› Issue (02): 226-230.

• Research Articles • Previous Articles     Next Articles

Pitting Corrosion of Cu-Zn-Al Shape Memory Alloy in Simulated Uterine Fluid

Bangyi CHEN, Chenghao LIANG, Daojun FU   

  1. School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China...
  • Received:2004-01-13 Revised:2004-06-28 Online:2005-03-28 Published:2009-10-10
  • Contact: Chenghao LIANG

Abstract: Electrochemical test technology and surface analysis method were employed to investigate the pitting corrosion of Cu-Zn-Al shape memory alloy in simulated uterine fluid. The results showed that the breakage of the breaking-renovating equilibrium of surface layers resulted in the pitting corrosion of Cu-Zn-Al shape memory alloy in simulated uterine fluid. The development of pitting corrosion was controlled by dissolution of surface layers. The critical pitting corrosion potential was 1.70 VSCE. The kinetics equation for the development of pitting corrosion for Cu-Zn-Al shape memory alloy in simulated uterine fluid was i0=465.68 t-0.5+1.5. Pitting appearances of pits could be two types: tortoise-shell, and anomaly abscess. Cl- ion facilitated the pitting corrosion of Cu-Zn-Al shape memory alloy by competing adsorption and concentrating on alloy surface at high positive potential.

Key words: Cu-Zn-Al Shape memory alloy, Simulated uterine fluid, Pitting corrosion