J Mater Sci Technol ›› 2004, Vol. 20 ›› Issue (02): 209-212.

• Research Articles • Previous Articles     Next Articles

Characteristics of Hydrogen Storage Alloy Mg2Ni Produced by Hydriding Combustion Synthesis

Qian LI, Qin LIN,Lijun JIANG,Guozhi ZHOU,Feng ZHAN,Qiang ZHENG   

  1. Research Center of Energy Materials and Technology, General Research Institute for Nonferrous Metal
  • Received:2004-04-19 Revised:1900-01-01 Online:2004-03-29 Published:2009-10-10
  • Contact: Qian LI

Abstract: A high activity and large capacity of hydrogen storage alloy Mg2Ni by hydriding combustion synthesis was investigated by means of pressure composition isotherms, X-ray diffraction and scanning electron microscopy. The results showed that the maximum hydrogen absorption capacity of Mg2Ni is 3.25 mass fraction at 523 K, just after synthesis without any activation. The relationships between the equilibrium plateau pressure and the temperature for Mg2Ni were lgp (0.1 MPa)=-3026/T+5.814 (523 K≤T ≤623 K) for hydriding and lgp (0.1 MPa)=-3613/T+6.715 (523 K≤T ≤623 K) for dehydriding. The kinetic equation is [-ln(1-α)]3/2 = kt and the apparent activation energy for the nucleation and growth-controlled hydrogen absorption and desorption were determined to be 64.3±2.31 kJ/(mol·H2) and 59.9±2.99 kJ/(mol·H2) respectively.

Key words: Hydriding combustion, Mg2Ni, Hydrogen storage property, Apparent activation energy