Hierarchical composite of biomass derived magnetic carbon framework and phytic acid doped polyanilne with prominent electromagnetic wave absorption capacity

doi:10.1016/j.jmst.2020.06.046

Abstract

Abstract:

To solve the electromagnetic pollution, herein, a CoFe₂O₄/C/PANI composite was developed by a green route, which was constructed with spinel of metal oxide, graphitized carbon and conductive polymer composites. Benefiting from the designable interfaces and increased dipoles, the microwave dielectric response capability can be boosted significantly and resulted in the enhanced microwave absorbing performance. As revealed by the reflection loss curve, the minimum reflection loss (RL_min) reached -51.81 dB at 12.4 GHz under a matched thickness of 2.57 mm. At 2.5 mm, the effective absorbing band covered 8.88 GHz, suggesting the desirable wideband feature. In our case, the method of utilization of a novel green way to fabricate multiple-component EM absorber can be a promising candidate for high-performance EM absorber.

Key words: Electromagnetic wave absorption, CoFe₂O₄/C/PANI, Interface polarization, Effective absorption bandwidth

Tianqi Hou, Zirui Jia, Ailing Feng, Zehua Zhou, Xuehua Liu, Hualiang Lv, Guanglei Wu. Hierarchical composite of biomass derived magnetic carbon framework and phytic acid doped polyanilne with prominent electromagnetic wave absorption capacity[J]. J. Mater. Sci. Technol., 2021, 68: 61-69.

Figures/Tables 8

Fig. 1. (a) Schematic illustration of the synthesis of CoFe2O4/C/PANI composite. XRD patterns (b), Raman spectra (c) and FT-IR spectra (d) of C, CoFe2O4/C and CoFe2O4/C/PANI composite.

Fig. 2. SEM images of carbon (a-c), CoFe2O4/C (d), SEM image (e-g) and EDX mapping (h) of CoFe2O4/C/PANI.

Fig. 3. TEM images of carbon (a, b) and CoFe2O4/C (c, d) under different magnifications, CoFe2O4/C/PANI under different magnifications (e, f).

Fig. 4. (a) XPS spectra of C, CoFe2O4/C and CoFe2O4/C/PANI. High-resolution XPS spectra of N 1s (b), C 1s (c) and O1s (d) spectrum of CoFe2O4/C/PANI.

Fig. 5. Permittivity (a, b), the permeability (c, d) of C, CoFe2O4/C and CoFe2O4/C/PANI composite.

Fig. 6. Three-dimensional RL and three-dimensional projection plots of C (a, b), CoFe2O4/C (c, d) and CoFe2O4/C/PANI (e, f) composite.Theoretical curves of RL versus frequency and thickness of C (g), CoFe2O4/C (h), CoFe2O4/C/PANI (i) composite and the RL curves (j) of three samples at the thickness of 2.5 mm. (m) The effective absorption bandwidth and RL values(<-10 dB) of CoFe2O4/C/PANI composite with different thicknesses.

Fig. 7. (a) Cole-Cole plots of CoFe2O4/C/PANI.(b) impedance matching and (c) attenuation constant α of C, CoFe2O4/C and CoFe2O4/C/PANI composite. (d) Schematic illustration of EM wave absorption mechanisms for CoFe2O4/C/PANI composite.

Table 1 Electromagnetic absorption properties of some related composites have been previously reported.

Sample	Mass ratio (wt.%)	RL_min (dB)	d (mm)	Frequency range (RL<-10 dB, GHz)	Refs.
C@NiCo₂O₄@Fe₃O₄	60	-43	3.4	2.1	[7]
C@CoFe₂O₄	30	-49.6	2.5	14.2 (1.5-5.0 mm)	[15]
Superhelical chiral PANI	30	-31.7	1.7	3.8	[23]
C@PANI	30	59.6	2.2	5.4	[24]
Ti₃C₂/Fe₃O₄/PANI	30	-40.3	2.4	1.9	[73]
PANI@GE	20	-64.3	2.9	5.1	[74]
PANI/GA	30	-42.3	3	3.2	[75]
NiFe₂O₄@PANI/PI	30	-19.2	1.5	5.1	[76]
GN@CoFe₂O₄@PANI	50	-47.7	1.6	5.7	[77]
CoFe₂O₄/C/PANI	20	-51.81	2.57	8.88	This work

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