材料科学与技术 ›› 2022, Vol. 120 ›› Issue (0): 129-138.DOI: 10.1016/j.jmst.2021.12.049
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收稿日期:2021-08-13修回日期:2021-10-22接受日期:2021-12-06出版日期:2022-09-01发布日期:2022-03-12
Interfacial engineering regulated by CeOx to boost efficiently alkaline overall water splitting and acidic hydrogen evolution reaction
Jian Chena,b, Zhen Hua,b, Yang Oua,b, Qinghua Zhangc, Xiaopeng Qia,b,*(
), Lin Guc, Tongxiang Lianga,b,*()
- aCollege of Rare Earth, Jiangxi University of Science and Technology, Ganzhou 341000, China
bFaculty of Materials Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, China
cInstitute of Physics, Chinese Academy of Science, Beijing 100190, China
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Received:2021-08-13Revised:2021-10-22Accepted:2021-12-06Online:2022-09-01Published:2022-03-12 -
Contact:Xiaopeng Qi,Tongxiang Liang -
About author:liang_tx@126.com (T. Liang).
* College of Rare Earth, Jiangxi University of Science and Technology, Ganzhou 341000, China. E-mail addresses: qxpai@163.com (X. Qi),
引用本文
. [J]. 材料科学与技术, 2022, 120(0): 129-138.
Jian Chen, Zhen Hu, Yang Ou, Qinghua Zhang, Xiaopeng Qi, Lin Gu, Tongxiang Liang. Interfacial engineering regulated by CeOx to boost efficiently alkaline overall water splitting and acidic hydrogen evolution reaction[J]. J. Mater. Sci. Technol., 2022, 120(0): 129-138.
Fig. 1. (a) Synthesis strategy for the formation of MoO2-CeOx/NF catalyst. SEM image of (b) MoO2-CeOx/NF; (c, d) TEM image of MoO2-CeOx/NF, (e) SAED images, (f, g) HR-TEM image of MoO2-CeOx/NF, (h) electron image and the corresponding elemental mappings of (i) Mo, (j) O, (k) Ce, and (l) Ni for MoO2-CeOx/NF.
Fig. 2. (a) XRD spectra and (b) survey XPS spectra of MoO2-CeOx/NF, MoO2/NF, and CeOx/NF. (c) Mo 3d XPS spectra of MoO2/NF and MoO2-CeOx/NF. (d) O 1 s XPS spectra of MoO2-CeOx/NF, MoO2/NF, and CeOx/NF. (e) Ce 3d XPS spectra of MoO2-CeOx/NF and CeOx/NF. (f) Ni 2p XPS spectra of MoO2-CeOx/NF, MoO2/NF, and CeOx/NF.
Fig. 3. (a) LSV curves and (b) Tafel plots, (c) Nyquist plots conducted at 100.0 mV (V vs. RHE) of MoO2-CeOx/NF, MoO2/NF, CeOx/NF, Pt/C, and NF, (d) Cdl of MoO2-CeOx/NF, MoO2/NF, CeOx/NF, and NF, (e) TOFs of MoO2-CeOx/NF, MoO2/NF, CeOx/NF, Pt/C, and NF, and (f) the stability of MoO2-CeOx/NF and Pt/C at -10.0 mA cm-2 in 1.0 M KOH.
Fig. 4. (a) LSV curves and the (b) corresponding overpotentials at 100 mA cm-2, (c) Tafel plots of MoO2-CeOx/NF, MoO2/NF, CeOx/NF, RuO2 and NF, (d) stability of MoO2-CeOx/NF and RuO2 at 100.0 mA cm-2 during a continuous operation in 1.0 M KOH. (e) LSV curves of Pt/C@NF//RuO2@NF, MoO2/NF//MoO2/NF and MoO2-CeOx/NF//MoO2-CeOx/NF for the overall water splitting process without iR compensation, and (f) stability of MoO2-CeOx/NF//MoO2-CeOx/NF and MoO2/NF//MoO2/NF at 20 mA cm-2 in 1.0 M KOH.
Fig. 5. (a) GC and water splitting device, (b) Quantity of H2 and O2 tested by GC method in 1.0 M KOH. (c) LSV curves and (d) Tafel plots, (e) Nyquist plots conducted at 100.0 mV (V vs. RHE) of MoO2-CeOx/NF, MoO2/NF, CeOx/NF, Pt/C, and NF, and the (f) stability of MoO2-CeOx/NF and Pt/C at -10.0 mA cm-2 in 0.5 M H2SO4.
Fig. 6. Calculation model diagrams of (a) MoO2, (b) Vo-MoO2, (c) CeOx and (d) Vo-MoO2-CeOx, PDOS programs of (e) MoO2, Vo-MoO2, CeOx and Vo-MoO2-CeOx.
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