生物分子辅助溶剂热合成硫化铋纳米棒

J. Mater. Sci. Technol. ›› 2010, Vol. 26 ›› Issue (5): 417-422.

• Research Articles • 上一篇下一篇

生物分子辅助溶剂热合成硫化铋纳米棒

钟家松¹,杨昕宇¹,梁晓娟¹,向卫东²,刘丽君³,张景峰⁴,蔡文⁵

1. 温州大学化学与材料工程学院
2. 温州大学化学与材料工程学院;同济大学材料科学与工程学院
3. 温州大学
4. 温州大学化学与工程学院
5. 同济大学材料科学与工程学院

收稿日期:2009-11-02 修回日期:2010-01-20 出版日期:2010-05-31 发布日期:2010-06-01
通讯作者: 向卫东
基金资助:
Bi2S3量子点玻璃三阶非线性光学性质的研究

Biomolecule-assisted Solvothermal Synthesis of Bismuth Sulfide Nanorods

Jiasong Zhong, Weidong Xiang, Lijun Liu, Xinyu Yang, Wen Cai, Jingfeng Zhang, Xiaojuan Liang

1) College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China
2) College of Materials Science and Engineering, Tongji University, Shanghai 200092, China

Received:2009-11-02 Revised:2010-01-20 Online:2010-05-31 Published:2010-06-01
Supported by:
National Natural Sciences Foundation of China (Grant Nos. 50772075 and 50972107)

摘要/Abstract

Abstract:

A simple biomolecule-assisted synthetic route has been successfully developed to prepare bismuth sulfide (Bi2S3) nanorods under solvothermal conditions. In the synthetic system, pentahydrate bismuth nitrate was employed to supply Bi source and L-cystine was used as sulfide source and complexing agent. The morphology, structure, and phase composition of the as-prepared Bi2S3 products were characterized by X-ray diffraction (XRD), energy dispersion spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), field-emission scanfining electron microscopy (FESEM), transmission electron microscopy (TEM), selected area electron diffraction (SAED), and high-resolution transmission electron microscopy (HRTEM). The experimental results show that the nanorods have uniform diameter of 100-200 nm and length of 2-4μm. The possible formation mechanism
for the bismuth sulfide nanorods was discussed.

Key words: Bismuth sulfide, Solvothermal, L-cystine, Nanorods

钟家松杨昕宇梁晓娟向卫东刘丽君张景峰蔡文. 生物分子辅助溶剂热合成硫化铋纳米棒[J]. J. Mater. Sci. Technol., 2010, 26(5): 417-422.

Jiasong Zhong Weidong Xiang Lijun Liu Xinyu Yang Wen Cai Jingfeng Zhang Xiaojuan Liang. Biomolecule-assisted Solvothermal Synthesis of Bismuth Sulfide Nanorods[J]. J Mater Sci Technol, 2010, 26(5): 417-422.

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生物分子辅助溶剂热合成硫化铋纳米棒

Biomolecule-assisted Solvothermal Synthesis of Bismuth Sulfide Nanorods

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