Fig. 14.. Equivalent circuit models used for fitting the impedance spectra of samples: (a) mill-scaled samples and (b) primer pre-coated samples. (Rs: solution resistance; CPEo: CPE of the reduction process of oxides; Ro: resistance of the reduction process of oxides; CPEi: CPE of the dissolution of iron; Ri: resistance of the dissolution of iron; CPEc: CPE of the primer layer; Rc: resistance of the primer layer).