Preparation of a tantalum-based MoSi2-Mo coating resistant to ultra-high-temperature thermal shock by a new two-step process

doi:10.1016/j.jmst.2020.11.059

J. Mater. Sci. Technol. ›› 2021, Vol. 81: 117-122.DOI: 10.1016/j.jmst.2020.11.059

• Research Article • Previous Articles Next Articles

Preparation of a tantalum-based MoSi₂-Mo coating resistant to ultra-high-temperature thermal shock by a new two-step process

Sainan Liu^b, Hongtai Shen^a^,^c, Jiawei Xu^a, Xiaojun Zhou^a, Jianfei Liu^a, Zhenyang Cai^a^,^c^,^*(), Xiaojun Zhao^a^,^c^,^*(), Lairong Xiao^a^,^c^,^*()

^aSchool of Materials Science and Engineering, Central South University, Changsha, Hunan, 410083, China
^bCenter for Mineral Materials, School of Minerals Processing and Bioengineering, Central South University, Changsha, 410083, Hunan, China
^cKey Laboratory of Non-ferrous Metal Materials Science and Engineering, Ministry of Education, Central South University, Changsha, 410083, China

Received:2020-07-27 Revised:2020-11-08 Accepted:2020-11-30 Published:2021-01-07 Online:2021-01-07
Contact: Zhenyang Cai,Xiaojun Zhao,Lairong Xiao
About author:xiaolr@csu.edu.cn (L. Xiao).
zhaoxj@csu.edu.cn (X. Zhao),
*School of Materials Science and Engineering, CentralSouth University, Changsha, Hunan, 410083, China.E-mail addresses: csuczy@csu.edu.cn (Z. Cai),

Abstract

Abstract:

To develop an ultra-high-temperature resistant coating for a reusable thermal protection system, the preparation of a tantalum-based MoSi₂-Mo coating by a new two-step process of multi-arc ion plating and halide activated pack cementation is presented. The coating has a dense structure and is well compatible with the tantalum substrate, which can be thermally shocked from room temperature to 1750 °C for 360 cycles without failure. The mechanism of the coating’s excellent resistance to high-temperature thermal shocks is that a strong-binding gradient interface and a dense SiO₂ oxide scale with good oxygen resistance are formed by the high-temperature self-diffusion of Si.

Key words: Thermal shock, MoSi₂, Tantalum, Multi-arc ion plating, Pack cementation

Sainan Liu, Hongtai Shen, Jiawei Xu, Xiaojun Zhou, Jianfei Liu, Zhenyang Cai, Xiaojun Zhao, Lairong Xiao. Preparation of a tantalum-based MoSi₂-Mo coating resistant to ultra-high-temperature thermal shock by a new two-step process[J]. J. Mater. Sci. Technol., 2021, 81: 117-122.

Figures/Tables 6

Fig. 1. Schematic diagram of the tantalum-based MoSi2-Mo coating preparation process.

Fig. 2. Schematic diagram of the tantalum-based MoSi2-Mo coating preparation process (a, d, g) and its corresponding microstructure (b, c, e, f, h, i).

Fig. 3. Microstructure and composition analysis of tantalum-based MoSi2-Mo coatings after different cycles of thermal shocks: (a) 120 cycles; (b) 240 cycles; (c) 360 cycles; (d) composition analysis results of Fig. 3(a).

Fig. 4. (a) HRTEM morphology for region A of Fig. 3(b); (b) HRTEM morphology for region B of Fig. 3(b).

Fig. 5. Cross-section structure morphology (a) and surface scanning analysis (b-e) of tantalum-based MoSi2-Mo coating after 300 cycles of thermal shocks.

Fig. 6. Surface morphology of tantalum-based MoSi2-Mo coating after different cycles of thermal shocks. (a) 120 cycles; (b) 240 cycles; (c) 300 cycles; (d) 360 cycles.

References 36

[1]	G. Baccolo, Nat. Chem. 7 (2015) 854. DOI URL
[2]	H. Bai, L. Zhong, S. Zhao, J. Wei, Y. Xu, J. Bai, J. Zhu, Appl. Surf. Sci. 493 (2019)1317-1325. DOI URL
[3]	B.S. Li, T.J. Marrow, D.E.J. Armstrong, Scr. Mater. 180 (2020) 77-82. DOI URL
[4]	Z. Lin, E.J. Lavernia, F.A. Mohamed, Acta Mater. 47 (4) (1999) 1181-1194. DOI URL
[5]	R. Pu, Y. Sun, J. Xu, X. Zhou, S. Li, B. Zhang, Z. Cai, S. Liu, X. Zhao, L. Xiao, Surf. Coat. Technol. 394 (2020), 125840. DOI URL
[6]	L. Xiao, X. Zhou, Y. Wang, R. Pu, G. Zhao, Z. Shen, Y. Huang, S. Liu, Z. Cai, X. Zhao, Corros. Sci. 173 (2020), 108751. DOI URL
[7]	L. Luo, Y. Zhou, Y. Zhang, X. Jiu, J. Liu, X. Zhu, Y. Wu, Trans. Nonferrous Met. Soc. China 29 (03) (2019) 525-537.
[8]	D. Glass, in: 15th A\|AA International Space Planes and Hypersonic Systemsand Technologies Conference, 2008, pp. 2008-2682.
[9]	L. Xiao, X. Xu, S. Liu, Z. Shen, S. Huang, W. Liu, Y. Peng, Y. Huang, J. Liu, Y. Nie, X. Zhao, Z. Cai, J. Eur. Ceram. Soc. 40 (2020) 3555-3561. DOI URL
[10]	W.A. Gibeaut, E.S. Bartlett, Coat. High-Temperature Mater. 2 (1966)113-206.
[11]	V.A. Avincola, M. Janek, U. Stegmaier, M. Steinbrück, H.J. Seifert, Oxid. Met. 85 (2015) 459-487. DOI URL
[12]	Z. Cai, D. Zhang, X. Chen, Y. Huang, Y. Peng, C. Xu, S. Huang, R. Pu, S. Liu, X. Zhao, L. Xiao, J. Eur. Ceram. Soc. 39 (2019) 2277-2286. DOI URL
[13]	Z. Cai, X. Zhao, D. Zhang, Y. Wu, J. Wen, G. Tian, Q. Cao, X. Tang, L. Xiao, S. Liu, Corros. Sci. 143 (2018) 116-128. DOI URL
[14]	Y. Chen, S. Chen, Surf. Coat. Technol. 215 (2013) 209-217. DOI URL
[15]	S. Majumdar, T.P. Sengupta, G.B. Kale, I.G. Sharma, Surf. Coat. Technol. 200 (2006) 3713-3718. DOI URL
[16]	D.D. Lawthers, L. Sama, ASD-TR-61-233, 74, 1961, pp. 1-80.
[17]	Z.H. Dong, X. Peng, F.H. Wang, Mater. Lett. 148 (2015) 76-78. DOI URL
[18]	C.M. Packer, R.A. Pekrkins, J. Less-Common Met. 37 (1974)361-378. DOI URL
[19]	C. Zenk, J.S.K.L. Gibson, V. Maier-Kiener, S. Neumeier, M. Göken, S. Korte-Kerzel, Acta Mater. 181 (2019) 385-398. DOI URL
[20]	M. Todai, K. Hagihara, K. Kishid, H. Inui, T. Nakano, Scr. Mater. 113 (2016)236-240. DOI URL
[21]	K. Hagihara, T. Nakano, S. Hata, O. Zhu, Y. Umakoshid, Scr. Mater. 62 (2010)613-616. DOI URL
[22]	Y. Gao, X. Guo, Y. Qiao, F. Luo, Appl. Surf. Sci. 504 (2020)144477. DOI URL
[23]	G. Yue, X. Guo, Y. Qiao, C. Zhou, Corros. Sci. 153 (2019) 283-291. DOI URL
[24]	J. Sun, Q.G. Fu, C.X. Huo, T. Li, C. Wang, C.Y. Cheng, G. J.Yang, J.C. Sun, J. Alloys Compd. 762 (2018) 922-932. DOI URL
[25]	J. Sun, Q.G. Fu, L.P. Guo, L. Wang, ACS Appl. Mater. Interfaces 8 (2016)15838-15847. DOI URL
[26]	C. Volders, P. Reinke, Surf. Sci. 681 (2019) 134-142. DOI URL
[27]	S.P. Sun, J.L. Zhu, S. Gu, X.P. Li, W.N. Lei, Y. Jiang, D.Q. Yi, G.H. Chen, Appl. Surf. Sci. 467- 468 (2019) 753-759. DOI
[28]	Z. Cai, Y. Wu, H. Liu, G. Tian, R. Pu, S. Piao, X. Tang, S. Liu, X. Zhao, L. Xiao, Mater. Des. 155 (2018) 463-474. DOI URL
[29]	G. Yue, X. Guo, Y. Qiao, Corros. Sci. 163 (2020), 108299. DOI URL
[30]	Z. Cai, S. Liu, L. Xiao, Z. Fang, W. Li, B. Zhang, Surf. Coat. Technol. 324 (2017)182-189. DOI URL
[31]	A.B. Gokhale, G.J. Abbaschian, J. Phase Equilib. 12 (1991) 493-498. DOI URL
[32]	M.E. Schlesinger, J. Phase Equilib. 15 (1994) 90-95. DOI URL
[33]	Y. Qiao, J. Kong, Q. Li, X. Guo, Surf. Coat. Technol. 327 (2017) 93-100. DOI URL
[34]	D.Y. Geng, Z.D. Zhang, M. Zhang, D. Li, X.P. Song, K.Y. Hu, Scr. Mater. 50 (7) (2004) 983-986. DOI URL
[35]	G.R. Li, L.S. Wang, G.J. Yang, Scr. Mater. 163 (2019) 142-147. DOI URL
[36]	G. Ouyang, S. Thimmaiah, M.J. Kramer, M. Akinc, P. Ritt, J.H. Perepezko, Appl. Surf. Sci. 470 (2019) 289-295. DOI URL

Preparation of a tantalum-based MoSi₂-Mo coating resistant to ultra-high-temperature thermal shock by a new two-step process

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