J. Mater. Sci. Technol. ›› 2020, Vol. 52: 127-135.DOI: 10.1016/j.jmst.2020.04.012
• Research Article • Previous Articles Next Articles
Ruoxian Wang, Gaowu Qin, Erlin Zhang()
Received:
2019-09-17
Revised:
2020-02-18
Accepted:
2020-02-27
Published:
2020-09-15
Online:
2020-09-18
Contact:
Erlin Zhang
Ruoxian Wang, Gaowu Qin, Erlin Zhang. Effect of Cu on Martensite Transformation of CoCrMo alloy for biomedical application[J]. J. Mater. Sci. Technol., 2020, 52: 127-135.
Alloys | Cr | Mo | Cu | Co |
---|---|---|---|---|
Co-0Cu | 29 | 6 | - | Bal. |
Co-1.5Cu | 30.6 | 6 | 1.3 | Bal. |
Co-2Cu | 28.9 | 6 | 1.9 | Bal. |
Co-4Cu | 28.8 | 5.9 | 3.9 | Bal. |
Table 1 Chemical composition of the Co-xCu alloys (wt%).
Alloys | Cr | Mo | Cu | Co |
---|---|---|---|---|
Co-0Cu | 29 | 6 | - | Bal. |
Co-1.5Cu | 30.6 | 6 | 1.3 | Bal. |
Co-2Cu | 28.9 | 6 | 1.9 | Bal. |
Co-4Cu | 28.8 | 5.9 | 3.9 | Bal. |
Fig. 2. Calculated fraction of the constituent phases in the alloy system varying with temperature: (a) Co-0Cu, (b) Co-1.5Cu, (c) Co-2Cu and (d) Co-4Cu alloys.
Alloys | Ms / K | Mf / K | Ms-Mf / K | Volume fraction of ε-phase | Volume fraction of σ phase |
---|---|---|---|---|---|
Co-0Cu | 1242 | 1240 | 2 | 1 | 0.1380 |
Co-1.5Cu | 1235 | 1225 | 10 | 0.9859 | 0.1622 |
Co-2Cu | 1216 | 1207 | 9 | 0.9560 | 0.1885 |
Co-4Cu | 1190 | 1161 | 29 | 0.8810 | 0.2480 |
Table 2 Temperature of phase transformation and maximum fraction of ε-phase and σ phase.
Alloys | Ms / K | Mf / K | Ms-Mf / K | Volume fraction of ε-phase | Volume fraction of σ phase |
---|---|---|---|---|---|
Co-0Cu | 1242 | 1240 | 2 | 1 | 0.1380 |
Co-1.5Cu | 1235 | 1225 | 10 | 0.9859 | 0.1622 |
Co-2Cu | 1216 | 1207 | 9 | 0.9560 | 0.1885 |
Co-4Cu | 1190 | 1161 | 29 | 0.8810 | 0.2480 |
Fig. 4. EBSD maps of alloys after different heat treatment: (a) Co-0Cu-1523 K, (b) Co-1.5Cu-1523 K, (c) Co- 2Cu-1523 K, (d) Co-4Cu-1523 K, (e) Co-0Cu-1173 K, (f) Co-1.5Cu-1173 K, (g) Co-2Cu-1173 K and (h) Co-4Cu-1173 K.
Alloys | 1523 K | 1173 K | ||
---|---|---|---|---|
fcc | hcp | fcc | hcp | |
Co-0Cu | 38.35 | 51.76 | 0 | 90.59 |
Co-1.5Cu | 25.53 | 65.08 | 4.72 | 92.6 |
Co-2Cu | 60.85 | 35.3 | 51.68 | 44.77 |
Co-4Cu | 73.64 | 25.79 | 46.17 | 47.34 |
Table 3 Phase fraction (%) detected from EBSD analysis.
Alloys | 1523 K | 1173 K | ||
---|---|---|---|---|
fcc | hcp | fcc | hcp | |
Co-0Cu | 38.35 | 51.76 | 0 | 90.59 |
Co-1.5Cu | 25.53 | 65.08 | 4.72 | 92.6 |
Co-2Cu | 60.85 | 35.3 | 51.68 | 44.77 |
Co-4Cu | 73.64 | 25.79 | 46.17 | 47.34 |
Fig. 5. SEM (a-h) images and BSE (i-l) images of Co-xCu alloys after different heat treatments: (a) Co-0Cu-1523 K, (b) Co-1.5Cu-1523 K, (c) Co-2Cu-1523 K, (d) Co-4Cu-1523 K, (e, i) Co-0Cu-1173 K, (f, j) Co-1.5Cu-1173 K, (g, k) Co-2Cu-1173 K and (h, l) Co-4Cu-1173 K.
Point | Co | Cr | Mo | Cu |
---|---|---|---|---|
A | 49.27 | 37.19 | 13.54 | 0 |
B | 18.27 | 7.02 | 1.86 | 72.86 |
C | 28.31 | 12.46 | 5.1 | 54.13 |
D | 29.57 | 12.65 | 3.44 | 54.35 |
Matrix | 62.61 | 27.31 | 8.87 | 1.22 |
Table 4 EDS results (wt%) obtained from the matrix of Co-4Cu-1173 K and the precipitates of Co-0Cu/4Cu-1173 K.
Point | Co | Cr | Mo | Cu |
---|---|---|---|---|
A | 49.27 | 37.19 | 13.54 | 0 |
B | 18.27 | 7.02 | 1.86 | 72.86 |
C | 28.31 | 12.46 | 5.1 | 54.13 |
D | 29.57 | 12.65 | 3.44 | 54.35 |
Matrix | 62.61 | 27.31 | 8.87 | 1.22 |
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