J. Mater. Sci. Technol. ›› 2020, Vol. 54: 190-195.DOI: 10.1016/j.jmst.2019.10.046

• Research Article • Previous Articles     Next Articles

Seeded growth of Ti-46Al-8Nb polysynthetically twinned crystals with an ultra-high elongation

Hao Jina,b, Qing Jiaa, Quangang Xiana, Ronghua Liua, Yuyou Cuia, Dongsheng Xua, Rui Yanga,*()   

  1. a Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, China
    b University of Chinese Academy of Sciences, Beijing, 100049, China
  • Received:2019-05-12 Revised:2019-08-29 Accepted:2019-10-24 Published:2020-10-01 Online:2020-10-21
  • Contact: Rui Yang

Abstract:

Large size polysynthetically twinned crystals of Ti-46Al-8Nb alloy with a parallel lamellar microstructure were successfully prepared using a Ti-43Al-3Si seed by our new operation. A large amount of columnar B2 phase paralleling to the growth direction was found in the final lamellar microstructure. Higher growth rate (>30?mm/h) led to the failure of seeding process. Based on these results, a new mechanism is proposed to describe the seeding process of the hypo-peritectic TiAl alloys. The peritectic α phase is suggested to directly nucleate from the melt, and then act as nucleus for transformed α phase in the subsequent β to α transformation. At the higher growth rate, the appearance of β phase secondary dendrites and homogeneous nucleation lead to the failure of seeding process. High Nb addition leads to a large amount of residual β phase, and these β dendrites finally evolve into B2 phase. The room temperature tensile elongation was measured to be 11.9-18.5% for Ti-46Al-8Nb PST crystals, which is the highest ever reported value for TiAl based alloys.

Key words: TiAl alloys, Polysynthetically twinned crystals, Peritectic solidification, Seeded growth, Ductility