J. Mater. Sci. Technol. ›› 2020, Vol. 40: 99-106.DOI: 10.1016/j.jmst.2019.08.033

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Strong, lightweight, and highly conductive CNT/Au/Cu wires from sputtering and electroplating methods

Thang Q. Tran*(), Jeremy Kong Yoong Lee, Amutha Chinnappan, W.A.D.M. Jayathilaka, Dongxiao Ji, Vishnu Vijay Kumar, Seeram Ramakrishna*()   

  1. Department of Mechanical Engineering, National University of Singapore, 9 Engineering Drive 1, EA-07-05, Singapore 117575, Singapore
  • Received:2019-07-14 Revised:2019-07-19 Accepted:2019-08-06 Published:2020-03-01 Online:2020-04-01
  • Contact: Tran Thang Q.,Ramakrishna Seeram

Abstract:

In this study, we present a 2-step deposition method via sputtering and electroplating that uses carbon nanotube (CNT) wires synthesized from a wet-spinning technique to produce high-performance CNT/Au/Cu composite wires. After the Au sputtering pre-treatment, the deposition of Cu on the CNT wires was found to be much more homogeneous due to improved wettability and reactivity of the wire surface. At different electrodeposition time, the mechanical strength of the CNT/Au/Cu composite wires could be as high as 0.74 GPa (~ 2 times stronger than metal wires) while their electrical conductivity could reach 4.65 × 105 S/cm (~ 80% of that for copper). More importantly, the CNT/Au/Cu composite wires with high CNT volume fraction are expected to be lightweight (up to 42% lower than Cu mass density), suggesting that our high-performance composite wires are a promising candidate to substitute conventional heavy metal wires in the future applications.

Key words: Carbon nanotube wires, Sputtering, Electrical conductivity, Electrodeposition