J. Mater. Sci. Technol. ›› 2019, Vol. 35 ›› Issue (6): 1175-1183.DOI: 10.1016/j.jmst.2018.12.014
Special Issue: High Entropy Alloys 2018-2020
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Cong Liua, Wenyi Penga(), C.S. Jianga, Hongmin Guoa, Jun Taoa, Xiaohua Dengb, Zhaoxia Chena
Received:
2018-08-06
Revised:
2018-10-13
Accepted:
2018-10-19
Online:
2019-06-20
Published:
2019-06-19
About author:
1 These authors contributed equally to this work.
Cong Liu, Wenyi Peng, C.S. Jiang, Hongmin Guo, Jun Tao, Xiaohua Deng, Zhaoxia Chen. Composition and phase structure dependence of mechanical and magnetic properties for AlCoCuFeNix high entropy alloys[J]. J. Mater. Sci. Technol., 2019, 35(6): 1175-1183.
Stabilized Phase | Elements | Alloys | Reference |
---|---|---|---|
FCC | Cu | CoCrFeNiCuxA1-x | [ |
Co | FeCoxNiCuAl | [ | |
BCC | Al | AlxCoCrFeNi | [ |
AlCoFeNi | [ | ||
Cr | AlCoCuFeNiCr | [ | |
Intermetallic | Zr | AlCoCrFeNiZrx | [ |
Ti | AlCoCrFeNiTix | [ | |
Si | CoFeNiSix | [ | |
Nb | AlCoCrFeNi | [ | |
(CoCrCuFeNi)100-xNbx | [ |
Table 1 Alloying elements and corresponding stabilized phase in HEAs.
Stabilized Phase | Elements | Alloys | Reference |
---|---|---|---|
FCC | Cu | CoCrFeNiCuxA1-x | [ |
Co | FeCoxNiCuAl | [ | |
BCC | Al | AlxCoCrFeNi | [ |
AlCoFeNi | [ | ||
Cr | AlCoCuFeNiCr | [ | |
Intermetallic | Zr | AlCoCrFeNiZrx | [ |
Ti | AlCoCrFeNiTix | [ | |
Si | CoFeNiSix | [ | |
Nb | AlCoCrFeNi | [ | |
(CoCrCuFeNi)100-xNbx | [ |
Alloy | I(110)B/I(111)F | Lattice constants (nm) | |
---|---|---|---|
FCC | BCC | ||
Ni0.5 | 3.16 | 0.3641 | 0.2885 |
Ni0.8 | 2.91 | 0.3630 | 0.2882 |
Ni1.0 | 0.94 | 0.3624 | 0.2878 |
Ni1.5 | 0.65 | 0.3612 | 0.2874 |
Ni2.0 | - | 0.3596 | - |
Ni3.0 | - | 0.3599 | - |
Table 2 Intensity ratio of the strongest peaks for FCC and BCC phases (I(110)B/I(111)F) and the lattice constants of FCC and BCC phases in the as-cast AlCoCuFeNix high-entropy alloys.
Alloy | I(110)B/I(111)F | Lattice constants (nm) | |
---|---|---|---|
FCC | BCC | ||
Ni0.5 | 3.16 | 0.3641 | 0.2885 |
Ni0.8 | 2.91 | 0.3630 | 0.2882 |
Ni1.0 | 0.94 | 0.3624 | 0.2878 |
Ni1.5 | 0.65 | 0.3612 | 0.2874 |
Ni2.0 | - | 0.3596 | - |
Ni3.0 | - | 0.3599 | - |
Alloys | Regions in | Al | Co | Cu | Fe | Ni |
---|---|---|---|---|---|---|
Ni3.0 | Nominal | 14.29 | 14.29 | 14.29 | 14.29 | 42.84 |
FCC | 14.73 | 14.95 | 13.65 | 14.42 | 42.25 | |
BCC | - | - | - | - | - |
Table 3 Nominal and experimental composition (at.%) of different regions in AlCoCuFeNi3.0 high entropy alloys.
Alloys | Regions in | Al | Co | Cu | Fe | Ni |
---|---|---|---|---|---|---|
Ni3.0 | Nominal | 14.29 | 14.29 | 14.29 | 14.29 | 42.84 |
FCC | 14.73 | 14.95 | 13.65 | 14.42 | 42.25 | |
BCC | - | - | - | - | - |
Element | Al | Co | Cu | Fe | Ni |
---|---|---|---|---|---|
Al | -19 | -1 | -11 | -22 | |
Co | 6 | -1 | 0 | ||
Cu | 13 | 4 | |||
Fe | -11 | ||||
Ni |
Table 4 Mixing enthalpies (kJ/mol) of atomic pairs between elements [26].
Element | Al | Co | Cu | Fe | Ni |
---|---|---|---|---|---|
Al | -19 | -1 | -11 | -22 | |
Co | 6 | -1 | 0 | ||
Cu | 13 | 4 | |||
Fe | -11 | ||||
Ni |
Alloys | Phase Structure | σ0.2 (MPa) | σmax (MPa) | εf (%) | Hardness (HV) | Ms (emu/g) | HC (Oe) | Remanence ratio (Mr/Ms) (%) |
---|---|---|---|---|---|---|---|---|
Ni0.5 | BCC + FCC + B2 | 929 | 1231 | 13.7 | 430.9 | 89.21 | 7.30 | 0.55 |
Ni0.8 | BCC + FCC + B2 | 1021 | 1465 | 12.3 | 420.0 | 83.92 | 3.77 | 0.29 |
Ni1.0 | FCC + BCC + B2 | 994 | 1609 | 24.5 | 391.4 | 73.73 | 5.81 | 0.37 |
Ni1.5 | FCC + BCC + B2 | 680 | 1725 | 35.9 | 323.8 | 63.58 | 13.70 | 1.40 |
Ni2.0 | FCC + BCC + B2 | 544 | - | - | 299.2 | 57.43 | 11.12 | 0.94 |
Ni3.0 | FCC | 268 | - | - | 279.6 | 54.68 | 24.81 | 9.35 |
Table 5 Phase structure, mechanical properties and magnetic parameters of AlCoCuFeNix high entropy alloys.
Alloys | Phase Structure | σ0.2 (MPa) | σmax (MPa) | εf (%) | Hardness (HV) | Ms (emu/g) | HC (Oe) | Remanence ratio (Mr/Ms) (%) |
---|---|---|---|---|---|---|---|---|
Ni0.5 | BCC + FCC + B2 | 929 | 1231 | 13.7 | 430.9 | 89.21 | 7.30 | 0.55 |
Ni0.8 | BCC + FCC + B2 | 1021 | 1465 | 12.3 | 420.0 | 83.92 | 3.77 | 0.29 |
Ni1.0 | FCC + BCC + B2 | 994 | 1609 | 24.5 | 391.4 | 73.73 | 5.81 | 0.37 |
Ni1.5 | FCC + BCC + B2 | 680 | 1725 | 35.9 | 323.8 | 63.58 | 13.70 | 1.40 |
Ni2.0 | FCC + BCC + B2 | 544 | - | - | 299.2 | 57.43 | 11.12 | 0.94 |
Ni3.0 | FCC | 268 | - | - | 279.6 | 54.68 | 24.81 | 9.35 |
Alloys | Phase structure | Ms (emu/g) | HC (Oe) | Reference |
---|---|---|---|---|
AlCoCuFeNi0.5 | BCC + B2 +FCC | 77.68 | 1.24 | Current study |
AlCoCrFeNi | BCC | 64.71 | 52 | [ |
AlCoCrFeNb0.75Ni | Laves+(Laves + BCC) | 10.31 | 94 | [ |
CoCrCuFeNiTi | FCC + Laves + Amorphous | 1.511 | - | [ |
FeCoNi | FCC | 155.7 | 2.37* | [ |
FeCoNiMn0.25Al0.75 | FCC | 101 | 3.37 | [ |
CoCrFeNiCuAl | ordered BCC + FCC | 38.18 | 45 | [ |
CoCrFeCuNi | FCC | 53.41 | 166 | [ |
Table 6 Comparison of saturation magnetization (Ms) and coercivity (HC) for HEAs.
Alloys | Phase structure | Ms (emu/g) | HC (Oe) | Reference |
---|---|---|---|---|
AlCoCuFeNi0.5 | BCC + B2 +FCC | 77.68 | 1.24 | Current study |
AlCoCrFeNi | BCC | 64.71 | 52 | [ |
AlCoCrFeNb0.75Ni | Laves+(Laves + BCC) | 10.31 | 94 | [ |
CoCrCuFeNiTi | FCC + Laves + Amorphous | 1.511 | - | [ |
FeCoNi | FCC | 155.7 | 2.37* | [ |
FeCoNiMn0.25Al0.75 | FCC | 101 | 3.37 | [ |
CoCrFeNiCuAl | ordered BCC + FCC | 38.18 | 45 | [ |
CoCrFeCuNi | FCC | 53.41 | 166 | [ |
Element | Crystal structure | r(?) | χ | VEC | Tm (K) |
---|---|---|---|---|---|
Al | FCC | 1.43 | 1.61 | 3 | 933.5 |
Co | HCP | 1.25 | 1.88 | 9 | 1770 |
Cu | FCC | 1.28 | 1.90 | 11 | 1358 |
Fe | BCC | 1.24 | 1.83 | 8 | 1811 |
Ni | FCC | 1.25 | 1.91 | 10 | 1728 |
Table 7 Parameters of the alloying elements at room temperature [30,31].
Element | Crystal structure | r(?) | χ | VEC | Tm (K) |
---|---|---|---|---|---|
Al | FCC | 1.43 | 1.61 | 3 | 933.5 |
Co | HCP | 1.25 | 1.88 | 9 | 1770 |
Cu | FCC | 1.28 | 1.90 | 11 | 1358 |
Fe | BCC | 1.24 | 1.83 | 8 | 1811 |
Ni | FCC | 1.25 | 1.91 | 10 | 1728 |
Alloys | δ (%) | ΔSmix (J·mol-1·K-1) | ΔHmix (kJ·mol-1) | Δχ | VEC | Tm (K) | Ω (kJ/mol) |
---|---|---|---|---|---|---|---|
Ni0.5 | 5.70 | 13.14 | -4.54 | 0.114 | 8.00 | 1497.0 | 4.33 |
Ni0.8 | 5.59 | 13.35 | -5.04 | 0.112 | 8.13 | 1511.5 | 4.00 |
Ni1.0 | 5.53 | 13.38 | -5.28 | 0.111 | 8.20 | 1520.1 | 3.85 |
Ni1.5 | 5.36 | 13.25 | -5.69 | 0.109 | 8.36 | 1539.0 | 3.59 |
Ni2.0 | 5.22 | 12.98 | -5.89 | 0.106 | 8.50 | 1554.7 | 3.43 |
Ni3.0 | 4.92 | 12.27 | -5.96 | 0.102 | 8.71 | 1579.5 | 3.25 |
Table 8 Values of δ, ΔSmix, ΔHmix, Δχ, VEC, Tm and Ω of AlCoCuFeNix high entropy alloys.
Alloys | δ (%) | ΔSmix (J·mol-1·K-1) | ΔHmix (kJ·mol-1) | Δχ | VEC | Tm (K) | Ω (kJ/mol) |
---|---|---|---|---|---|---|---|
Ni0.5 | 5.70 | 13.14 | -4.54 | 0.114 | 8.00 | 1497.0 | 4.33 |
Ni0.8 | 5.59 | 13.35 | -5.04 | 0.112 | 8.13 | 1511.5 | 4.00 |
Ni1.0 | 5.53 | 13.38 | -5.28 | 0.111 | 8.20 | 1520.1 | 3.85 |
Ni1.5 | 5.36 | 13.25 | -5.69 | 0.109 | 8.36 | 1539.0 | 3.59 |
Ni2.0 | 5.22 | 12.98 | -5.89 | 0.106 | 8.50 | 1554.7 | 3.43 |
Ni3.0 | 4.92 | 12.27 | -5.96 | 0.102 | 8.71 | 1579.5 | 3.25 |
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