J. Mater. Sci. Technol. ›› 2014, Vol. 30 ›› Issue (9): 928-933.DOI: 10.1016/j.jmst.2014.06.009

• Orginal Article • Previous Articles     Next Articles

Effect of Fe Content on the Interfacial Reliability of SnAgCu/Fe-Ni Solder Joints

Hao Zhang1, Qing-Sheng Zhu1, Zhi-Quan Liu1, *, Li Zhang2, Hongyan Guo2, Chi-Ming Lai2   

  1. 1 Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China; 2 Jiangyin Changdian Advanced Packaging Co., Ltd., Jiangyin 214431, China
  • Received:2014-01-18 Online:2014-09-20 Published:2014-09-30
  • Contact: * Corresponding author. Prof., Ph.D.; Tel./Fax: t86 24 83970826;E-mail address:zqliu@imr.ac.cn (Z.-Q. Liu).

Abstract: Fe-Ni films with compositions of Fe-75Ni, Fe-50Ni, and Fe-30Ni were used as under bump metallization (UBM) to evaluate the interfacial reliability of SnAgCu/Fe-Ni solder joints through ball shear test, high temperature storage, and temperature cycling. The shear strengths for Fe-75Ni, Fe-50Ni, and Fe-30Ni solder joints after reflow were 42.57, 53.94 and 53.98 MPa, respectively, which were all satisfied the requirement of industrialization (>34.3 MPa). High temperature storage was conducted at 150, 175 and 200 °C. It was found that higher Fe content in Fe-Ni layer had the ability to inhibit the mutual diffusion at interface region below 150 °C, and the growth speed of intermetallic compound (IMC) decreased with increasing Fe concentration. When stored at 200 °C, the IMC thickness reached a limit for all three films after 4 days, and some cracks occurred at the interface between IMC and Fe-Ni layer. The activation energies for the growth of FeSn2 on Fe-30Ni, Fe-50Ni, and Fe-75Ni films were calculated as 246, 185, and 81 kJ/mol, respectively. Temperature cycling tests revealed that SnAgCu/Fe-50Ni solder joint had the lowest failure rate (less than 10%), and had the best interfacial reliability among three compositions.

Key words: Fe-Ni alloy, Under bump metallization (UBM), Intermetallic compound (IMC), Reliability, High temperature storage, Temperature cycling