Nanoengineering Titania for High Rate Lithium Storage: A Review

doi:10.1016/j.jmst.2012.11.017

Abstract

Abstract:

Nanostructured titania have been intensively investigated as anode materials of Li-ion batteries for their excellent high rate performance. The size effects of TiO₂ polymorphs (mainly rutile, anatase and TiO₂-B) on their electrochemical performance and the latest efforts in nanoengineering titania anodes through enhancing their ionic or electronic transportation or both are reviewed in this work. We suppose that micron-or submicronsized porous structures assembled by TiO₂ nanoparticles, nanowires/nanotubes or nanosheets with a high percentage of exposing high reactive facets together with a conductive percolating network are ideal anodes not only for high rate lithium storage but also for high packing densities of the active materials.

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Key words: Li-ion batteries, Titania, Nanostructures, Rate capability

Chunhai Jiang, Jinsong Zhang. Nanoengineering Titania for High Rate Lithium Storage: A Review[J]. J. Mater. Sci. Technol., 2013, 29(2): 97-122.

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