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Cor Sci Pro Tech  2009, Vol. 21 Issue (3): 236-238    DOI:
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STUDY ON CORROSION OF MAGNESIUM ALLOY IN SIMULATED COOLING  WATER BY MEANS OF IN SITU SPECTROSCOPIC ELLIPSOMETRY
LI Ling-jie1、2; LEI Jing-lei1; HE Dong-hai1; XU Hui1; ZHANG Sheng-tao1; PAN Fu-sheng2
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Abstract  

    In situ spectroscopic ellipsometry was employed to investigate the corrosion behavior of AZ40 magnesium alloy in a simulated cooling water without and with molybdate inhibitor.By deconvoluting the ellipsometric data with a one-layer model,the evolution of the refractive indices and the thickness of the interface layer of electrode-medium were obtained.Based on the deconvolution results,three regimes, which were dissolution of native oxide film,formation of adsorption film and precipitation of corrosion products,were proposed for the corrosion process of magnesium alloys in the simulated cooling water.The addition of molybdate weakened the dissolution of the native oxide film and made the adsorption film and the precipitated film much compact,which was responsible for the effective inhibition of molybdate on corrosion of magnesium alloys in the simulated cooling water.

Key words:  spectroscopic ellipsometry      magnesium alloy      simulated cooling water      corrosion     
Received:  01 September 2008     

TG174.4

 
Corresponding Authors:  LI Ling-jie     E-mail:  ljli@cqu.edu.cn

Cite this article: 

LI Ling-jie; LEI Jing-lei; HE Dong-hai; XU Hui; ZHANG Sheng-tao; PAN Fu-sheng. STUDY ON CORROSION OF MAGNESIUM ALLOY IN SIMULATED COOLING  WATER BY MEANS OF IN SITU SPECTROSCOPIC ELLIPSOMETRY. Cor Sci Pro Tech, 2009, 21(3): 236-238.

URL: 

https://www.cspt.org.cn/EN/     OR     https://www.cspt.org.cn/EN/Y2009/V21/I3/236

[1]阿查姆 R M A,巴夏拉 N M,梁民基,尹树百.椭圆偏振测量术和偏振光[M].北京: 科学出版社,1986.261.
[2]Vedam K.Spectroscopic ellipsometry:a historical overview[J].Thin Solid Films,1998,313-314:1.
[3]Fujiwara H.Spectroscopic Ellipsometry:Principles and Applications[M].John Wiley & Sons,Inc.,2007.5.
[4]Lei J L,Li L J,Kostecki R,et al.Characterization of the SEI layer on LiMn2O4 cathode with in situ spectroscopic ellipsometry[J].Journal of the Electrochemical Society,2005,152(4):A774.
[5]Li L J,Lei J L,Yu S H,et al.In situ ellipsometric studies of formation kinetics of rare earth metal conversion coatings on magnesium alloys[J].Physica Status Solidi (c),2008,5(5):1308.
[6]李凌杰,雷惊雷,于生海,等.钼酸盐对镁合金在模拟冷却水中腐蚀的抑制作用[J].化工学报,2008,59(5):1223.
[7]Dean J.Lange′s Handbook of Chemistry(15th edition)[M].McGRAW HILL,INC,1999.8,15.
[8]Mu G N,Li X H,Qu Q,et al.Molybdate and tungstate as corrosion inhibitors for cold rolling steel in hydrochloric acid solution[J].Corrosion Science, 2006,48(2):445.
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