J. Mater. Sci. Technol. ›› 2020, Vol. 38: 64-72.DOI: 10.1016/j.jmst.2019.07.041
• Research Article • Previous Articles Next Articles
Received:
2019-06-08
Revised:
2019-07-15
Accepted:
2019-07-16
Published:
2020-02-01
Online:
2020-02-10
Contact:
Wang Nan
Yinli Peng, Nan Wang. Effect of phase-separated patterns on the formation of core-shell structure[J]. J. Mater. Sci. Technol., 2020, 38: 64-72.
Fig. 1. Two cross-sectional microstructures obtained in Fe-Sn alloy by drop tube processing. The experimental condition can refer to Ref. [8]. The initial compositions of (a) and (b) are Fe-68 wt% Sn and Fe-60 wt%Sn, respectively.
Fig. 2. Phase diagram of SCN-H2O system. The symbols correspond to experimental conditions in S5H, S6H, and S7H. The region covered by dashed line is unstable for spinodally decomposed phase separation.
Compositions | Binodal Temperature, Tb (K) | Spinodal temperature, Ts (K) | Annealed temperature, Ta (K) | ||
---|---|---|---|---|---|
293 | 313 | 323 | |||
S5H | 331.1 | 331.1 | SD | SD | SD |
S6H | 329.2 | 322.9 | SD | SD | NG |
S7H | 323.7 | — | NG | NG | NG |
Table 1 Thermal conditions for realizing SD- and NG-type phase separation in different systems.
Compositions | Binodal Temperature, Tb (K) | Spinodal temperature, Ts (K) | Annealed temperature, Ta (K) | ||
---|---|---|---|---|---|
293 | 313 | 323 | |||
S5H | 331.1 | 331.1 | SD | SD | SD |
S6H | 329.2 | 322.9 | SD | SD | NG |
S7H | 323.7 | — | NG | NG | NG |
Fig. 4. Snapshots of phase separation occurring in S5H (a) and S7H (b) at 313 K. The dotted line shows a plane interface of combination. All the images have identical scale bar.
Fig. 7. Morphologies of S5H (a) and S7H (b) at early stage with the same temperatures, (c) the radii of SD-D and NG-D, and (d) the average velocity of two type droplets measured during the evolution. The images have the same bar.
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