Correlation of Raw Materials and Waterborne Polyurethane Properties by Sequence Similarity Analysis

doi:10.1016/j.jmst.2016.02.006

J. Mater. Sci. Technol. ›› 2016, Vol. 32 ›› Issue (7): 687-694.DOI: 10.1016/j.jmst.2016.02.006

• Orginal Article • Previous Articles Next Articles

Correlation of Raw Materials and Waterborne Polyurethane Properties by Sequence Similarity Analysis

Xing Zhou^{1, 2}, Changqing Fang^{1, 2, *}, Jing Chen³, Shujuan Li¹, Yan Li¹, Wanqing Lei¹

1 School of Mechanical and Precision Instrument Engineering, Xi'an University of Technology, Xi'an 710048, China; 2 Faculty of Printing, Packaging Engineering and Digital Media Technology, Xi'an University of Technology, Xi'an 710048, China; 3 Wuxue High School, Hubei 435400, China

Received:2015-12-08 Revised:2015-12-28 Online:2016-07-10 Published:2016-10-10
Contact: Corresponding author. Ph.D.; Tel.: +86 29 82312038; Fax: +86 29 82312512. E-mail address: fcqxaut@163.com (C. Fang).
Supported by:
The authors acknowledge the financial support provided by Program for New Century Excellent Talents in University by the Ministry of Education of China (Grant No. NCET-12-1045), the Shaanxi Programs for Science and Technology Development (No. 2010K01-096) and Ph.D. Innovation Fund Projects of Xi'an University of Technology (No. 310-252071501).

Abstract

Abstract: Anionomer-type waterborne polyurethane dispersions (PUDs) were obtained from poly (propylene glycol) (PPG), isophoronediisocyanate (IPDI) and dimethylolpropionic acid (DMPA) through a modified prepolymer isocyanate process. Two series of polyurethanes were prepared (Groups A and B) and a new prediction model based on grey relational analysis is introduced to predict the impact order of raw materials on several properties, such as solids content, viscosity, acid number and electrolytic stability of polyurethanes. It is found that the model can successfully predict the impact of raw materials on the properties through the designed demonstration experiments. Furthermore, the results of the prediction model show that DMPA plays a key role in viscosity, partial acid values and electrolytic stability.

Key words: Dispersion, Material properties, Model, Polyurethane (PU), Stability, Synthesis

Xing Zhou, Changqing Fang, Jing Chen, Shujuan Li, Yan Li, Wanqing Lei. Correlation of Raw Materials and Waterborne Polyurethane Properties by Sequence Similarity Analysis[J]. J. Mater. Sci. Technol., 2016, 32(7): 687-694.

Figures/Tables 4

Correlation among raw materials, bulk structure and properties of polyurethane: (a) common route of “raw materials → structure → properties”, which is much complex; (b) direct correlation between raw materials and properties. (The ellipsis represents the other elliptical raw materials, bulk structure and properties of polyurethane).

FTIR spectra of PUDs with different hard-/soft-segment molar ratio.

(a) Structure and 1H NMR spectrum of sample A1; (b) 1H NMR spectrum of all samples, (1) sample A1, (2) sample A2, (3) sample A3.

Properties of waterborne polyurethane dispersions for demonstration.

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Correlation of Raw Materials and Waterborne Polyurethane Properties by Sequence Similarity Analysis

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