J. Mater. Sci. Technol. ›› 2013, Vol. 29 ›› Issue (4): 353-358.DOI: 10.1016/j.jmst.2013.01.014

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Influence of Nano-Al Concentrates on the Corrosion Resistance of Epoxy Coatings

Yongchun Liang1), Fu-Chun Liu2), Ming Nie1), Shuyan Zhao2), Jiedong Lin1), En-Hou Han2)   

  1. 1) The Electric Power Research Institute of Guangdong Power Grid Corporation, Guangzhou 510080, China
    2) State Key Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences,
    Shenyang 110016, China
  • Received:2012-08-10 Revised:2012-09-20 Online:2013-04-30 Published:2013-03-28
  • Contact: Fu-Chun Liu
  • Supported by:

    National Key Technology R&D Pro­gram (Grant No. 2012BAB15B00) for supporting these studies.

Abstract:

A two-stage process was used to produce nano-composite epoxy coatings. The first step involved preparing nano-Al concentrates with high concentration and low viscosity, and the second step produced nano-composite epoxy coatings by mixing the nano-Al concentrates and epoxy resin. Later, the coating was examined with immersion and salt spray tests. The coatings were characterized by electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The results showed that the 5% nano-Al significantly improves the corrosion resistance of the coatings. There are two effects of nano-Al on the coating. Nano-Al is corroded initially to protect the substrate from corrosion, and then the aluminum oxide and aluminum hydroxide were produced after corrosion of nano-Al, which hindered the transmission of corrosion fluid into the coatings.

 

Key words: Nanometer metal, Organic coatings, Salt spray test, Electrochemical impedance spectroscopy